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Polyhydric Alcohol Pulping at Atmospheric Pressure: An Effective Method for Organosolv Pulping of Softwoods

机译:大气压多元醇制浆:一种软木有机溶剂制浆的有效方法

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摘要

Polyhydric alcohol pulping was developed to separate components of low-quality softwoods that are produced by thinning and improvement cutting as well as to establish a self supporting pulping system. Propylene glycol (PG) was superior to ethylene glycol (EG) as solvent for polyhydric alcohol pulping at atmospheric pressure. PG pulping of fir, 1arch and cedar, with sulfuric acid as a catalyst, gave satisfactory pulps with few rejects and a very low level of residual lignin as compared with EG pulping. The PG pulps were readily bleached to approximately Kappa number l and 80/100 brightness by one treatment with sodium chlorite. The yie1d of bleached pulp from fir was 44.7/100 based on chips. The bleached pulps had very high a-cellulose content and crystallinity, and their mechanical properties were similar to those of kraft pulp. Therefore, polyhydric alcohol pulping appears to be promising for pulping of softwoods by an organosoly method. 5f411-415
机译:开发了多元醇制浆技术,以分离通过稀释和改良切割而生产的劣质软木成分,并建立自支撑制浆系统。作为常压下多元醇制浆的溶剂,丙二醇(PG)优于乙二醇(EG)。与硫酸制浆相比,冷杉,1arch和雪松的PG制浆,以硫酸为催化剂,制得的纸浆令人满意,几乎没有废品,残留的木质素含量非常低。通过用亚氯酸钠进行一次处理,容易将PG纸浆漂白至大约κ值和80/100的亮度。冷杉的漂白纸浆收率为44.7 / 100(基于碎屑)。漂白后的纸浆具有很高的α-纤维素含量和结晶度,其机械性能与牛皮纸浆相似。因此,多元醇制浆似乎有望通过有机溶胶法制浆软木。 5f411-415

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