A fixed domain model for microsegregation during solidification of binary alloys

摘要

A fixed-domain numerical model for microsegregation during alloy solidi. cation is developed. The phenomena of solute partitioning at the moving solid/liquid interface and subsequent redistribution by diffusion in the solid and liquid phases have been formulated using volumetric terms. A solute balance equation valid for the whole domain comprising the solid and liquid phases has been obtained in terms of the liquid concentration. The effects of microstructure coarsening on microsegregation has been described and included in the present model. Numerical experiments and comparisons have been carried out between the present fixed-domain model, previous deforming-domain models, and the exact analytical solutions available in the literature. Good agreement has been observed between the predictions of the present fixed-domain model and the exact analytical solutions. Further extensions of the present model for the analysis of two-dimensional microsegregation have been also reported.