Evaluation of various types of Al-MCM-41 materials as catalysts in biomass pyrolysis for the production of bio-fuels and chemicals

摘要

MCM-41, is one of the latest members of the mesoporous family of materials. They possess a hexagonal array of uniform mesopores (1.4-10 nm), high surface areas (>1000 m~2/g) and moderate acidity. Due to these properties the MCM-41 materials are currently under study in a variety of processes as catalysts or catalyst supports. The objective of this study was to evaluate different types of MCM-41 materials as potential catalysts in the catalytic biomass pyrolysis process. We expected that the very high pore size and the mild acidity of these materials could be beneficial to reformulate the high molecular weight primary molecules from biomass pyrolysis producing useful chemical (and especially phenolic compounds) and lighter bio-oil with less heavy molecules. Three different samples of Al-MCM-41 materials (with different Si/Al ratio) and three metal containing mesoporous samples (Cu-Al-MCM-41, Fe-Al-MCM-41 and Zn-Al-MCM-41) have been synthesised, characterized and tested as catalysts in the biomass catalytic pyrolysis process using a fixed bed pyrolysis combined with a fixed catalytic reactor and two different types of biomass feeds. Compared to conventional (non-catalytic) pyrolysis, it was found that the presence of the MCM-41 material alters significantly the quality of the pyrolysis products. All catalysts were found to increase the amount of phenolic compounds, which are very important in the chemical (adhesives) industry. A low Si/Al ratio was found to have a positive effect on product yields and composition. Fe-Al-MCM-41 and Cu-Al-MCM-41 are the best metal-containing catalysts in terms of phenols production. The presence of the Al-MCM-41 material was also found to decrease the fraction of undesirable oxygenated compounds in the bio-oil produced, which is an indication that the bio-oil produced is more stable.