Study on coal chars combustion under O_2/CO_2 atmosphere with fractal random pore model

摘要

When predicting the variation of pore structure during O_2/CO_2 combustion of coal chars using the random pore model (RPM), it is impossible to calculate exactly the structure parameter ψ from the pore characteristics. The values of structure parameter ψ, which were calculated based on its fractal feature at various carbon conversions, should be almost constant. However, this investigation exhibited a drastic increase of ψ at the end of combustion reaction. In this work, structure parameter ψ of the RPM was modified according to the experimental analysis and a new model, fractal random pore model (FRPM), was constructed. Compared with other models such as RPM, discrete random pore model (DRPM), the Struis model (Model Ⅰ) and the Liu model (Model Ⅱ), it was found that fractal random pore model was more accurate to describe coal chars combustion, especially at higher conversions. Using the FRPM, O_2/CO_2 isotherm combustion of coal chars were analyzed at different temperatures.