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Environmental aspects of a field-scale underground coal gasification trial in a shallow coal seam at the Experimental Mine Barbara in Poland

机译:波兰巴巴拉实验性煤矿的浅煤层田间规模地下煤气化试验的环境因素

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摘要

A study on the environmental impacts of underground coal gasification (UCG) was conducted during a field-scale, in situ coal gasification experiment at the Experimental Mine "Barbara" in Poland. This two-week experiment was a part of a technological effort aiming to produce hydrogen-rich product gas using the UCG technology. As groundwater pollution is recognised to be the most serious environmental risk related to UCG, extensive investigations on the formation, release, and migration of contaminants were conducted. The study revealed a wide range of organic and inorganic contaminants that were characteristic for the UCG. The main organic contaminants were phenolic compounds and aromatic hydrocarbons (mono- and polycyclic). Among the inorganic species, heavy metals, ammonia and cyanides were the most serious group of contaminants. These compounds were identified in the post-processing effluents and in groundwater near the test site. The impact of the gasification process on the groundwater, however, was small and tended to effectively decrease over the time and distance from the cavity zone. A possible negative environmental impact of the gasification by-products, including ash and char left underground, was also evaluated. This study revealed that these post-gasification residuals are the main source of toxic trace elements, but the most volatile species, such as Hg, As and Se, tended to escape the cavity zone with the product gas during gasification phase. Monitoring activities detected no chemical hazards on the surface during the course of the experiment and after its termination; however, UCG-induced thermal effects on surface were observed.
机译:在波兰的“ Barbara”实验性矿场进行了现场规模的原位煤气化实验期间,对地下煤气化(UCG)的环境影响进行了研究。这个为期两周的实验是旨在使用UCG技术生产富氢产品气的技术工作的一部分。由于地下水污染被认为是与UCG有关的最严重的环境风险,因此对污染物的形成,释放和迁移进行了广泛的研究。研究发现,UCG具有多种有机和无机污染物。主要的有机污染物是酚类化合物和芳烃(单环和多环)。在无机物质中,重金属,氨和氰化物是最严重的污染物。这些化合物在后处理废水和测试地点附近的地下水中被鉴定出。但是,气化过程对地下水的影响很小,并且随着时间和距离空腔区域的增加,趋于有效降低。还评估了气化副产物(包括留在地下的灰烬和木炭)可能对环境造成的负面影响。这项研究表明,这些气化后的残留物是有毒微量元素的主要来源,但是在气化阶段,最易挥发的物质(例如Hg,As和Se)倾向于随产品气体一起逸出空腔区域。在实验过程中和终止后,监测活动未发现表面化学危险;但是,观察到了UCG引起的表面热效应。

著录项

  • 来源
    《Fuel》 |2013年第11期|196-208|共13页
  • 作者单位

    Glowny Instytut Gornictwa (Central Mining Institute), Plac Gwarkow 1, 40-166 Katowice, Poland;

    Glowny Instytut Gornictwa (Central Mining Institute), Plac Gwarkow 1, 40-166 Katowice, Poland;

    Glowny Instytut Gornictwa (Central Mining Institute), Plac Gwarkow 1, 40-166 Katowice, Poland;

    Glowny Instytut Gornictwa (Central Mining Institute), Plac Gwarkow 1, 40-166 Katowice, Poland;

  • 收录信息 美国《科学引文索引》(SCI);美国《工程索引》(EI);
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    Underground coal gasification; Groundwater pollution; Hydrogen production;

    机译:地下煤气化;地下水污染;制氢;

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