Cost-effective activated carbon (AC) production from partial substitution of coal with red mud (RM) as additive for SO_2 and NO_X abatement at low temperature

摘要

Red mud (RM) was used as additive for activated carbon (AC) production and the results show that RM could adjust its physiochemical texture and performance. RM promotes the development of AC's pore structure and surface chemistry. The as-derived granular 10RM/AC' surface area of micropore, total specific area, and total pore volume is up to 451 m(2)/g, 848 m(2)/g, 0.49 cm(3)/g, which are 11%, 49%, and 88% higher than AC, respectively. Meanwhile, O/C and pi-pi* group significantly increased with the addition of RM. RM's addition promotes desulfurization activity and lowers denitrification efficiency. 10RM/AC shows maximum sulfur capacity (65.1 mg/g), which is 17.9% higher than that of AC (55.2 mg/g). However, ACs' nitrate capacity has declined from 0.86 mg/g to 0.40 mg/g due to the poisoning effect of RM's high CaO/Na2O content, etc. The presence of SO2 obviously promoted the nitrate capacity from 0.94 mg/g to 1.16 mg/g due to the new acid site's formation by sulfate species through SO2 and NH3. Meanwhile, the inorganic components (Fe-, Ca- and Na- containing species) in ACs from RM catalyze SCR reaction and the related mechanism was proposed. The results of this research provided an approach and preliminary information for utilizing industrial waste RM for cost-effective AC preparation.