Enhanced disinfection of Escherichla coli and bacteriophage MS2 in water using a copper and silver loaded titanium dioxide nanowire membrane

摘要

Titanium dioxide (TiO_2) is a widely used photocatalyst that has been demonstrated for microorganism disinfection in drinking water. In this study, a new material with a novel structure, silver and copper loaded TiO_2 nanowire membrane (Cu-Ag-TiO_2) was prepared and evaluated for its efficiency to inactivate E. coli and bacteriophage MS2. Enhanced photo-activated bactericidal and virucidal activities were obtained by the Cu-Ag-TiO_2 membrane than by the TiO_2, Ag-TiO_2 and Cu-TiO_2 membranes under both dark and UV light illumination. The better performance was attributed to the synergies of enhanced membrane photoactivity by loading silver and copper on the membrane and the synergistic effect between the free silver and copper ions in water. At the end of a 30 min test of deadend filtration under 254 nm UV irradiation, the Cu-Ag-TiO_2 membrane was able to obtain an E. coli removal of 7.68 log and bacteriophage MS2 removal of 4.02 log, which have met the US EPA standard. The free metal ions coming off the membrane have concentrations of less than 10 ppb in the water effluent, far below the US EPA maximum contaminant level for silver and copper ions in drinking water. Therefore, the photo-activated disinfection by the Cu-Ag-TiO_2 membrane is a viable technique for meeting drinking water treatment standards of microbiological water purifiers.