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Modelling the Thermal Decompositions of Wood and Leaves Under a Nitrogen Atmosphere

机译:在氮气氛下模拟木材和树叶的热分解

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The thermal decomposition of six different samples of wood and leaves in nitrogen ahs been studied by using dynamic thermogravimetry. In the experiments two main weight loss processes took place and the total weight loss at 500 deg. C was over 95/100 in all six cases. By means of the Doyle method, the two processes were found to fit most closely the plot for the second-order equation in the form dα/dt = k(1-α)~2, and each of the weight loss processes was found to be controlled, respectively, by two dominant reactions as the temperature increases. It was inferred that competing reactions occur during the overall temperature interval for all the six samples.
机译:通过动态热重法研究了六种不同的木材和树叶样品在氮气中的热分解。在实验中,发生了两个主要的减肥过程,总减肥在500度下进行。在所有六种情况下,C均超过95/100。通过Doyle方法,发现这两个过程最接近二阶方程的图,形式为dα/ dt = k(1-α)〜2,并且发现每个减肥过程都可以随着温度升高,分别由两个主要反应控制。可以推断,在所有六个样品的整个温度间隔内都发生竞争性反应。

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