首页> 外文期刊>The European Physical Journal B - Condensed Matter and Complex Systems >Tuning the physical parameters towards optimal polymer-wrapped single-walled carbon nanotubes dispersions
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Tuning the physical parameters towards optimal polymer-wrapped single-walled carbon nanotubes dispersions

机译:针对最佳的聚合物包裹单壁碳纳米管分散体调节物理参数

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摘要

Solubilization of single-walled carbon nanotubes (SWNTs) has been essential for the understanding of their physical properties. Ultrasonication followed by centrifugation has been generally used for the preparation of SWNT dispersion in presence of different surfactants or conjugated polymers. However, the experimental condition and procedure show lab-to-lab dissimilarities. In this study, we report on the preparation and optical characterization of SWNTs dispersed with poly(9,9-di-n-octylfluorenyl-2,7-diyl) (PFO). The effects of several processing parameters are investigated, such as sonication time, polymer concentration and centrifugation speed. Optical spectroscopic techniques including absorption and photoluminescence in the near-infrared spectral regions are used for the evaluation of the different SWNT dispersions. The optimal parameters to obtain isolated SWNTs are identified.
机译:单壁碳纳米管(SWNT)的增溶对于理解其物理性质至关重要。在不同的表面活性剂或共轭聚合物的存在下,超声处理然后离心通常已用于制备SWNT分散体。但是,实验条件和步骤显示了实验室之间的差异。在这项研究中,我们报告与分散的聚(9,9-二-正辛基芴基-2,7-二基)(PFO)的单壁碳纳米管的制备和光学表征。研究了几个处理参数的影响,例如超声处理时间,聚合物浓度和离心速度。包括近红外光谱区域中的吸收和光致发光在内的光谱技术用于评估不同的SWNT色散。确定获得分离的SWNT的最佳参数。

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