IR-Spektren von TMP und CTMP, hergestellt aus Kiefernholz und mitteldichten Faserplatten (MDF)

摘要

IR-spectra of TMP and CTMP prepared from pine wood and UF-bonded MDF made from pine wood show characteristic differences. The typical band for carbonyl groups (C=O-groups) at wave number about 1740 cm-1 is strong in pine wood, but appears relatively weak in TMP and especially in CTMP made thereof. In UF-bonded MDF made from pine wood the band at about 1740 cm-1 is very weak compared to that in pine wood. Moreover, no significant difference in the IR-spectrum between TMP and CTMP made from UF-bonded MDF seems to exist. This is attributed to the fact that during thermo-mechanical pulping of UF-bonded boards hydrolytic degradation of the resin takes place enhancing the formation of ammonia which increases the pH-value of the fibres and leads therefore to chemo-thermo-mechanical pulping.