Tracing of Industrial Aerosol Sources in an Urban Environment Using Pb, Sr, and Nd Isotopes

摘要

A comprehensive Pb-Sr-Nd isotope tracer study of atmospheric trace metal pollution has been performed in the urban environment of Strasbourg-Kehl. Filter dust of the principal pollutant sources (waste incinerators, thermal power plant and steel plant) and soot of car and ship exhausts have been analyzed. In addition tree barks (as biomonitors) and PM10 have been analyzed to trace and determine the distribution of the pollution in the environment. The industrial sources have highly variable εNd values (-9.7 and -12.5 for incinerators and -17.5 for steel plant). Much higher εNd values have been found for soot of car exhausts (-6 and -6.9). These high values make the Nd isotope system a powerful tool for the discrimination of traffic emissions but especially for the identification of diesel derived particles in the urban environment. The ~(206)Pb/~(207)Pb isotope ratios of gasoline are low (1.089) compared to diesel soot (1.159). The ~(206)Pb/~(207)Pb ratios of 1.151-1.152 for the steel plant and 1.152 for the solid waste incinerator are close to the Pb isotope ratio of diesel. The ~(87)Sr/ ~(86)Sr isotope ratios of the principal industrial sources vary significantly: 0.7095 for the domestic solid waste incinerator, 0.709 for the steel plant, and 0.7087 for car exhaust soot. PM10 aerosols collected in the urban center of Strasbourg show the influence of the pollutant sources at 3-7 km distance from the center. Most of the aerosols Pb isotopic compositions suggest Pb admixtures from at least three sources: a natural background and in function of the wind direction the domestic waste incinerator (S-wind) or the steel plant and the chemical waste incinerator (NE-wind). The traffic contribution can only be estimated with help of Nd isotopes. Therefore the clear identification of different pollutant sources inthe urban environment is only possible by combining the three different isotope systems and is based on the fact that significant differences exist between the Pb, Sr, and Nd isotope ratios of the natural atmospheric background and pollutants containing Pb, Sr, and Nd of industrial origin with similar variable ~(206)Pb/~(207)Pb, ~(87)Sr/ ~(86)Sr, and ~(143)Nd/~(144)Nd.