Carbon Dioxide Capture by Functionalized Solid Amine Sorbents with Simulated Flue Gas Conditions

摘要

A novel solid amine sorbent was prepared using KIT-6-type mesoporous silica modified with tetraethylenepentamine (TEPA). Its adsorption behavior toward CO_2 from simulated flue gases is investigated using an adsorption column. The adsorption capacities at temperatures of 303,313,333,343, and 353 Kare 2.10,2.29,2.58, 2.85, and2.71 mmolg"1, respectively. Experimental adsorption isotherms were obtained, and the average isosteric heat of adsorption was 43.8 kj/mol. The adsorption capacity increases to 3.2 mmol g"1 when the relative humidity (RH) of the simulated flue gas reaches 37%. The adsorption capacity is inhibited slightly by the presence of SO_2 at concentrations lower than 300 ppm but is not significantly influenced by NO at concentrations up to 400 ppm. The adsorbent is completely regenerated in 10 min at 393 K and a pressure of 5 KPa, with expected consumption energy of about 1.41 MJ kg CO_2. The adsorption capacity remains almost the same after 10 cycles of adsorption/regeneration with adsorption conditions of 10 vol % CO_2, 100 ppm SO_2, 200 ppm NO, 100% relative humidity, and a temperature of 393 K. The solid amine sorbent, KIT-6(TEPA), performs excellently for CO_2 capture and its separation from flue gas.