Continuous Bulk FeCuC Aerogel with Ultradispersed Metal Nanoparticles: An Efficient 3D Heterogeneous Electro-Fenton Cathode over a Wide Range of pH 3-9

摘要

Novel iron-copper-carbon (FeCuC) aerogel was fabricated through a one-step process from metal-resin precursors and then activated with CO_2 and N_2 in environmentally friendly way. The activated FeCuC aerogel was applied in a heterogeneous electro-Fenton (EF) process and exhibited higher mineralization efficiency than homogeneous EF technology. High total organic carbon (TOC) removal of organic pollutants with activated FeCuC aerogel was achieved at a wide range of pH values (3-9). The chemical oxygen demand (COD) of real dyeing wastewater was below China's discharge standard after 30 min of treatment, and the specific energy consumption was low (9.2 kW·h·kg~(-1)COD~(-1)), corresponding to a power consumption of only ～0.34 kW·h per ton of wastewater. The enhanced mineralization efficiency of FeCuC aerogel was mostly attributable to ultradispersed metallic Fe-Cu nanoparticles embedded in 3D carbon matrix and the CO_2-N_2 treatment The CO_2 activation enhanced the accessibility of the aerogel's pores, and the secondary N_2 activation enlarged the porosity and regenerated the ultradispersed zerovalent iron (Fe~0) with reductive carbon. Cu~0 acted as a reduction promoter for interfacial electron transfer. Moreover, activated FeCuC aerogel presented low iron leaching (＜0.1 ppm) in acidic solution and can be molded into different sizes with high flexibility. Thus, this material could be used as a low-cost cathode and efficient heterogeneous EF technology for actual wastewater treatment.