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New composites based on low-density polyethylene and rice husk: Elemental and thermal characteristics

机译:基于低密度聚乙烯和稻壳的新型复合材料:元素和热学特性

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We developed new composites by combining the solid waste from Low-Density Polyethylene in the form of plastic bag (PB) and biomass from rice husk (RH),in the form of (RH)_x(PB)_(1-X)„ (x = (1, 0.9, 0.7, 0.5)), as alternative fuels for electrical energy sources, and for providing the best solution to reduce environmental pollution. Elemental compositions were obtained by using proximate analysis, ultimate analysis, and X-ray fluorescence spectroscopy, and the thermal characteristics were obtained from thermogravimetric analysis. The compositions of carbon and hydrogen from the ultimate analysis show significant increases of 20-30% with increasing PB in the composite. The activation energy for RH is 101.22 kj/mol; for x = 0.9 and 0.7, this increases by 4 and 6 magnitude, respectively, and for x = 0.5, shows remarkable increase to 165.30 kj/mol. The range of temperature of about 480-660℃ is required for combustion of the composites (RH)_x(PB)(1-x) (x = (1, 0.9, 0.7, 0.5)) to perform the complete combustion process and produce high energy. In addition, the calorific value was determined by using bomb calorimetry, and shows value for RH of 13.44 MJ/kg, which increases about 30-40% with increasing PB content, indicating that PB has a strong effect of increasing the energy realized to generate electricity.
机译:我们结合了低密度聚乙烯的塑料袋(PB)形式的固体废物和稻壳(RH)的生物质形式(RH)_x(PB)_(1-X)的形式开发了新的复合材料(x =(1,0.9,0.7,0.5)),作为电能的替代燃料,并为减少环境污染提供了最佳解决方案。通过使用近似分析,最终分析和X射线荧光光谱法获得元素组成,并通过热重分析获得热特性。最终分析表明,碳和氢的组成随复合物中PB的增加而显着增加20-30%。 RH的活化能为101.22 kj / mol;对于x = 0.9和0.7,这分别增加了4和6个数量级,对于x = 0.5,则显示出显着增加到165.30 kj / mol。复合材料(RH)_x(PB)(1-x)(x =(1,0.9,0.7,0.5))的燃烧需要大约480-660℃的温度范围,以完成整个燃烧过程并产生高能量。另外,通过使用炸弹量热法测定了发热量,其相对湿度为13.44 MJ / kg,随着PB含量的增加而增加了约30-40%,这表明PB具有增加实现能量产生的强大作用。电力。

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