Geochemistry of severely biodegraded oils in the Carboniferous volcanic reservoir of the Chepaizi Uplift, Junggar Basin, NW China

摘要

A substantial amount of petroleum was recently discovered in the Carboniferous volcanic reservoir of the Chepaizi Uplift in the western Junggar Basin, yet the source is still indefinitive. Geochemical investigation indicates that the Carboniferous oils from the eastern and western Chepaizi Uplift are characterized by different source facies, although they are all typically of lacustrine origin. The eastern oils exhibit a restricted, clastic starved, highly reducing hypersaline condition during source rock deposition, which is distinct from the western oils. The Carboniferous oils were subjected to biodegradation ranging from rank 6 to rank 9, as indicated by the presence of 25-norhopane, evident depletion of hopanes and regular steranes, and even selective reduction of tricyclic terpanes. The maturities for the Carboniferous oils correspond to the onset of oil generation. The eastern oils contain lower (C-19 + C-20)TT/(C-23 + C-24)TT and C19TT/C21TT, and lighter stable carbon isotopes than the western ones, correlating well with the Middle Permian Wuerhe (P(2)w) source rocks and the Jurassic source rocks, respectively. The good correlation of tricyclic terpanes source-related parameters further implies less contribution to the eastern oils by the Carboniferous source rocks.