Titanium tritide radioisotope heat source development: Palladium-coated titanium hydriding kinetics and tritium loading tests

摘要

For applications requiring 5-20 mW electrical power for 10-20 years, tritium-based radioisotope thermoelectric generators may be an alternative to Pu-238 based devices. Tritium can be stored compactly on a titanium bed. However, one of the main challenges then becomes loading the heat source at temperatures compatible with existing bismuth telluride thermoelectric module technology (<300 ℃). We find that a 180 nm palladium coating enables titanium to be loaded with hydrogen isotopes without the typical 400-500 ℃ vacuum activation step. Further, we observe that the hydriding kinetics of Pd coated and vacuum activated Ti are similar; both of which can be described by the Mintz-Bloch adherent film model, where the rate of hydrogen absorption is controlled by diffusion through an adherent metal-hydride layer. Finally, we design a prototype heat source vessel and demonstrate that it can be loaded completely, at temperatures below 300 ℃, in less than 10 h.