Synergistic Improvement in Coating with UV Aging Resistance and Anti-Corrosion via La-Doped CeO2 Powders

摘要

Benefitting from a suitable band gap, ceria is an excellent material for UV shielding. By solid solution doping and specific micromorphology, its band gap can be effectively controlled. In this paper, ceria doped with lanthanum via oxalate precipitation is combined with a high-temperature roasting process. The properties of the prepared samples are characterized by UV–Vis diffuse reflectance spectroscopy (DRS), Raman, XRD, FESEM and XPS. The absorption threshold of materials is clearly red-shifted in the ultraviolet band, which originates from the electron-phonon generation. To further reveal the mechanism, the density function theory calculation (DFT) is implemented to study the influence of lanthanum concentrations on ceria’s band gap. It is demonstrated that the band gap can even be narrowed to 2.97 eV by optimizing the sintering temperature and lanthanum-doped concentration. To investigate its improved anti-aging properties under ultraviolet rays, different amounts of 5% lanthanum-doped ceria is mixed with an Al-based coating and then coated on the Q235 steel. Combined with an ultraviolet light irradiation experiment and electrochemical test technology, the corrosion resistance of the modified coatings is evaluated. The coating with 20% La-doped ceria provides the best corrosion resistance performance.