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Design Strategies for Enhanced Conductivity in Metal–Organic Frameworks

机译:金属有机框架中电导率增强的设计策略

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Metal–organic frameworks (MOFs) are a class of materials which exhibit permanent porosity, high surface area, and crystallinity. As a highly tunable middle ground between heterogeneous and homogeneous species, MOFs have the potential to suit a wide variety of applications, many of which require conductive materials. The continued development of conductive MOFs has provided an ever-growing library of materials with both intrinsic and guest-promoted conductivity, and factors which limit or enhance conductivity in MOFs have become more apparent. In this Outlook, the factors which are believed to influence the future of MOF conductivity most heavily are highlighted along with proposed methods of further developing these fields. Fundamental studies derived from these methods may provide pathways to raise conductivity across a wide range of MOF structures.
机译:金属有机框架(MOFS)是一类具有永久性孔隙,高表面积和结晶度的材料。 作为异质和均匀物种之间的高度可调谐的中间地面,MOF具有适合各种应用的潜力,其中许多需要导电材料。 导电MOF的持续发展已经为具有内在和客人促进的电导率的有史以来的材料图书馆提供了一个不断增长的材料图书馆,以及限制或增强MOF的导电性的因素变得更加明显。 在这一前景中,据称影响MOF电导率的未来的因素最大地被突出地突出了进一步发展这些领域的方法。 来自这些方法的基本研究可以提供途径,以提高各种MOF结构的电导率。

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