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Effect of a promising CSESE pretreatment on the morphological structure and properties of jute fibers

机译:有前途的CSESE预处理对黄麻纤维形态结构和性质的影响

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Plant fiber has a complex aggregated structure, high crystallinity and a large number of hydrogen bonds, and has low chemical reaction activity. Therefore, in order to improve the reactivity, the plant fiber needs to be pretreated before chemical modification. Therefore, the pretreatment method has an important influence on the chemical modification of plant fibers. In this paper, Jute fibers were successively treated by particular continuous screw-extrusion steam explosion (CSESE). The effects on the morphological ructure, composition, thermal and crystalline properties of jute fibers before and after treated were investigated. Scanning electron microscopy (SEM) showed that the morphological structure changed significantly after CSESE pretreatment, the diameter was smaller, the surface cracks and the specific surface area increased. There was no new functional groups appeared in fourier transform infrared spectroscopy (FTIR). Composition analysis demonstrated that the content of hemicellulose and extractive decreased, but cellulose and lignin increased. The crystallinity of JSE increased from 66.31 % to 70.19 %. X-ray photoelectron spectroscopy (XPS) suggested that the cellulose and lignin content increased. Thermogravimetric analysis (TGA) demonstrated that the initial decomposition temperature of JSE increased from 334.4 to 355.2°C. DMA indicated that the Tg of JSE reduced from 92.6 to 90.0°C. Therefore, for jute fiber, the CSESE pretreatment is an effective and promising pretreatment method for further chemical modification, biofuels and chemical products.
机译:植物纤维具有复杂的聚集结构,高结晶度和大量氢键,具有低化学反应活性。因此,为了提高反应性,在化学修饰之前需要预处理植物纤维。因此,预处理方法对植物纤维的化学改性具有重要影响。本文通过特定的连续螺旋挤出蒸汽爆炸(CSESE)连续处理黄麻纤维。研究了对处理处理前后黄麻纤维的形态鲁克纹,组成,热和结晶性能的影响。扫描电子显微镜(SEM)表明,CSEESE预处理后的形态结构显着变化,直径较小,表面裂缝和比表面积增加。傅里叶变换红外光谱(FTIR)中没有出现新的功能组。成分分析表明,半纤维素的含量和萃取的含量降低,但纤维素和木质素增加。 JSE的结晶度从66.31%增加到70.19%。 X射线光电子能谱(XPS)表明纤维素和木质素含量增加。热重分析(TGA)证明JSE的初始分解温度从334.4增加到355.2°C。 DMA表示JSE的TG从92.6降至90.0°C。因此,对于黄麻纤维,CSESE预处理是一种有效且有前进的预处理方法,用于进一步的化学改性,生物燃料和化学产品。

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