Aromatics to triquinanes: Studies on synthesis and photo reaction of endo-tricyclo [5.2.2.02,6] undecanes.

摘要

Synthesis of endo-tricyclo[5.2.2.02.6]undecanes having a /3, y.enone chromophore and their photochemical reaction upon triplet excitation is described. The key reaction for the synthesis of tricycloundecanes (9-13) involves generation and interception of