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Characterization and flexibility properties of UV LED cured acrylic pressure-sensitive adhesives for flexible displays

机译:UV LED固化丙烯酸压敏粘合剂的表征和柔韧性柔性显示器

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The era of the Internet of Things (IoT) is becoming a reality, and the display equipment is at its center. The display device is the window that connects the IoT and humans, and is evolving into various form factors convenient to human use, such as foldable mobile phone, flexible wearable device, paper-like display, and rollable TV. Even though transparent flexible electrodes and substrates have been developed, their assembly remains a challenge. Therefore, the importance of optically clear acrylic pressure-sensitive adhesives (PSAs) that ensure device integrity by easily stretched and mitigating the stress during repeated stretching and bending process is being emphasized. In this study, elongation and recovery features were identifiable as key flexible properties of PSAs. These properties were estimated by measuring shear strain and strain recovery using a universal testing machine and by dynamic mechanical analytics respectively. Compared to conventional UV metal halide curing, a newly introduced ultraviolet light-emitting diode (UV LED) curing process resulted in different PSA property variables, namely UV exposure intensity and UV exposure time. Fully cured acrylic PSA realized under UV LED exposure level 30 for 8?s demonstrated the highest shear strain with excellent strain recovery of ~23,500% and 94% respectively. Under these conditions, effective material adhesion performance was achieved while retaining optical transparency and thus fulfilling the dual property requirement for non-opaque material adhesiveness necessary for use in flexible displays.
机译:东西互联网(物联网)的时代正在成为一个现实,并且显示器设备位于其中心。显示设备是连接物联网和人类的窗口,并且正在发展成为人类使用方便的各种形式因素,例如可折叠的移动电话,灵活的可穿戴设备,纸张涂布纸和可卷曲的电视。即使已经开发出透明的柔性电极和基板,它们的组装仍然是一个挑战。因此,正在强调通过容易地拉伸和减轻重复拉伸和弯曲过程中的易于拉伸和缓解应力来确保器件完整性的光学透明丙烯酸压敏粘合剂(PSAS)的重要性。在本研究中,伸长和恢复特征是可识别的,作为PSA的关键灵活性。通过使用通用试验机和动态机械分析测量剪切应变和应变恢复来估计这些性质。与传统的UV金属卤化物固化相比,新引入的紫外线发光二极管(UV LED)固化过程导致不同的PSA性变量,即紫外线暴露强度和UV暴露时间。在UV LED暴露等级30下实现的完全固化的丙烯酸PSA用于8μS的8℃,分别显示出优异的应变回收率〜23,500%和94%。在这些条件下,在保持光学透明度的同时实现了有效的材料粘合性能,从而实现了在柔性显示器中使用所需的非不透明材料粘合性的双重性能。

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