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Experimental study on evolution of oxidation behavior on high-temperature continuous casting slab surface

机译:高温连铸板表面氧化行为演化的实验研究

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The oxidation kinetics, oxide layers composition and thicknesses of X70 steel, Y55 steel and 304 stainless steel are investigated. The results show that the oxidation rate of X70 steel increases rapidly at 1000?°C, while that of Y55 steel and 304 stainless steel increases rapidly at 1100?°C. The oxidation kinetic coefficients of X70 steel, Y55 steel and 304 stainless steel are exp (10.7), exp (11.58) and exp (30.15), respectively, and the apparent activation energy of oxide layer are 196879.7?J/mol, 207608.1?J/mol and 469284.3?J/mol, respectively. The cross-sectional morphology and element distribution of oxide layer are obtained. With the oxidation time increases from 30min to 80?min?at 1100?°C, the oxide layer thickness of X70 steel and Y55 steel increases by 1242.33?μm and 965.59?μm respectively when the weight of steels increases by 1?mg/mm2, and the oxide layer of Y55 steel is denser than that of X70 steel. A variable temperature oxidation mathematical model of the slab surface is established to predict the oxide layer thickness of slab surface.
机译:研究了氧化动力学,X70钢,Y55钢和304不锈钢的氧化物层组合物和厚度。结果表明,X70钢的氧化速率在1000℃的1000℃下迅速增加,而Y55钢和304不锈钢的速度迅速增加1100℃。 X70钢,Y55钢和304不锈钢的氧化动力学系数分别为EXP(10.7),EXP(11.58)和EXP(30.15),氧化物层的表观激活能量为196879.7?J / Mol,207608.1?J. / mol和469284.3?j / mol。获得氧化物层的横截面形态和元素分布。氧化时间从30分钟增加到80?分钟?在1100?℃下,当钢的重量增加1Ωmg/ mm2时,x70钢和y55钢的氧化物层厚度分别增加1242.33Ωμm和965.59Ωμm并且Y55钢的氧化物层比X70钢更密集。建立了平板表面的可变温度氧化数学模型,以预测板坯表面的氧化物层厚度。

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