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Microwave and Induction Heating-Assisted Biosynthesis of 12CaO 7Al2O3 Electride from Aloe Vera Leaf Extract

机译:微波和感应加热辅助生物合成12CaO 7Al2O3电热的电热,来自芦荟叶提取物

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The white powders used as precursor powders for the synthesis of 12CaO×7Al2O3 electride (C12A7:e-) were prepared by biosynthesis method using Aloe vera extract and microwave assisted synthesis. The C12A7:e- crystals were synthesized by induction heating process under a reducing atmosphere at different times of 3, 4 and 5 min. The structure of C12A7:e- powders was characterized by X-ray diffraction. The XRD analysis revealed that pure C12A7:e- powders were obtained from white precursor powders with an induction heating process time of 5 min. To confirm that the white precursor powders were transformed into C12A7:e- after induction heating process for 3, 4 and 5 min, the optical absorption spectra of powders were investigated by an UV-Vis diffuse reflectance spectrometer in the wavelength range of 200 – 800 nm. The results show the optical absorption bands at 2.8 eV for the white precursor powders with induction heating time of 3, 4 and 5 min. This is due to the C12A7 was transformed into electride (C12A7:e-). Therefore, the results on the optical absorption spectra are in good agreement with the XRD results.
机译:使用芦荟提取物和微波辅助合成,通过生物合成方法制备用作合成12CaO×7Al2O3电导(C12A7:E-)的前体粉末的白色粉末。 C12A7:通过在不同时间为3,4和5分钟的还原气氛下通过感应加热过程合成E-晶体。 C12A7的结构:X射线衍射的特征在于X射线衍射。 XRD分析显示,纯C12A7:从白色前体粉末获得电粉,诱导加热处理时间为5分钟。为了确认将白色前体粉末转化为C12A7:E-在感应加热过程3,4和5分钟后,通过UV-Vis漫反射光谱仪在200 - 800波长范围内研究粉末的光学吸收光谱纳米。结果表明,对于28eV的白色前体粉末,具有3,4和5分钟的白色前体粉末的光学吸收带。这是由于C12A7转化到电极(C12A7:E-)中。因此,光学吸收光谱的结果与XRD结果吻合良好。

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