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STUDYON TREATMENTOF OILFIELD SEWAGE BY CHEMICAL OXIDATION AND FLOCCULATION BASED ON ORTHOGONALTEST DESIGN

机译:基于正交试验设计的化学氧化和絮凝处理油田污水的研究

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At present,most oil fields have entered the middle and later stages of oil exploitation,and the water content of the crude oil produced has reached 70% to 80%,and some oil fields have even reached 90%.After separation of oil and water,a large amount of oily sewage is generated.If the oily sewage is directly discharged without treatment,it will not only cause pollution of the soil and water sources,but also cause economic losses to the country,but also endanger the interests of the oil field.In view of the characteristics of high suspended matter and organic matter concentration in the oil field sewage,the flocculation method is used to pretreat the oil field sewage to remove suspended solids; after flocculation and sedimentation treatment,the oil field sewage is subjected to deep treatment of supercritical water oxidation to remove the high concentration of oil field sewage refractory organic matter.Optimize the operation parameters of each process and draw the conclusions: (1) The best treatment conditions obtained by the flocculation sedimentation process are: when the pH is 7,the dosage of PAC is 1200 mg/L and the dosage of PAM is 50 mg/L,the treatment effect is the best.The pretreatment of flocculation agent makes COD removal reached 60%. (2) Under sufficient oxygen supply conditions, supercritical water oxidation has a good treatment effect.When the reaction temperature is 44,the reaction pressure is 24 MPa,and the reaction residence time is 10 min,COD removal can be much greater than 90 %.Orthogonal test results show that the reaction temperature is the most critical factor affecting the treatment effect.
机译:目前,大多数油田已进入石油开采的中间和后期阶段,并且所产生的原油的水含量达到70%至80%,和一些油田甚至已达到的油和水的90%。经分离,大量含油污水是generated.If含油污水不经处理直接排放,这不仅会造成土壤和水源的污染,还会造成经济损失的国家,而且还危及石油利益的高悬浮物和在油田污水中的有机物浓度特性field.In视图,絮凝方法用于预处理油田污水以去除悬浮的固体;絮凝和沉降处理后,油田污水进行超临界水氧化的深度处理以除去高浓度油田污水耐火有机matter.Optimize的各处理的运算参数并得出结论:(1)最好的治疗通过絮凝沉淀处理得到的条件是:当pH为7,PAC的剂量是1200毫克/升和PAM的剂量是50毫克/升,治疗效果是絮凝剂的best.The预处理使COD去除率达到了60%。 (2)在足够的氧供应的条件下,超临界水氧化具有良好的治疗effect.When反应温度为44时,反应压力为24兆帕,和反应停留时间是10分钟,COD去除率可以是远远大于90% .Orthogonal测试结果表明,该反应温度是影响治疗效果的最关键因素。

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