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Control and Transfer of Chirality Within Well-Defined Tripodal Supramolecular Cages

机译:在定义明确定义的三架子夹架内的手性控制和转移

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The development of new strategies to turn achiral artificial hosts into highly desirable chiral receptors is a crucial challenge in order to advance the fields of asymmetric transformations and enantioselective sensing. Over the past few years, C3 symmetrical cages have emerged as interesting class of supramolecular hosts that have been reported as efficient scaffolds for chirality dynamics (such as generation, control, and transfer). On this basis, this mini review, which summarizes the existing examples of chirality control and propagation in tripodal supramolecular cages, aims at discussing the benefits and perspectives of this approach.
机译:将成立的人工宿主转化为高度理想的手性受体的新策略是一个至关重要的挑战,以推进不对称转化和对映选择性感应的田间。在过去的几年里,C3对称笼子已经出现为有趣的超分子宿主,已被报告为手术动力学的有效支架(例如生成,控制和转移)。在此基础上,这个迷你审查总结了三架子上扑克笼中的手性控制和传播的现有例子,旨在讨论这种方法的好处和观点。

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