Platinum decorated alumina particles have the potential of being a highly (cost-)effective catalyst. The particles are synthesized from platinum(II) acetylacetonate dissolved in a mixture of isopropanol and acetic acid with dispersed alumina carriers. The process is simulated by means of large eddy simulation with reaction kinetics and aerosol dynamics modeling. A two mixture fraction approach for tabulated chemistry with a thickened flame model is used to consider the complex reaction kinetics of the solvent spray combustion. Diffusion is described followings Ficks law with a unity Lewis number for the gas phase species, whereas the particle diffusion coefficients are calculated according to the kinetic theory. An extended model for aerosol dynamics, capable of predicting deposition rate and surface particle growth, is derived from the classical sectional technique. The simulations are compared and validated with product particle characteristics obtained from the experimental observations. Distributions for different locations within the simulation domain show the evolution of particle sizes deposited on the alumina particle surface, and transmission electron microscopy (TEM) images of the composite particles are shown in comparison to 3D particles ballistically reconstructed from simulation data. The ratio of deposited platinum on the alumina carrier particles and the mean diameters of the deposited particles are in good agreement with the experimental observation. Overall, the new method has demonstrated to be suitable for simulating the particle decoration process.
展开▼
