catena-Poly[[chloridotris(1,3-thiazolidine-2-thione-κS)cadmium(II)]-μ-chlorido]

摘要

The synthesis and characterization of poly[dichloridotri(1,3-thiazolidine-2-thione)cadmium(II)], [CdCl 2 (C 3 H 5 NS 2 ) 3 ] n , prepared from CdCl 2 ·H 2 O and C 3 H 5 NS 2 (tzdSH) in a 1:3 ratio, are described. The Cd II cation is coordinated by three 1,3-thiazolidine-2-thione molecules and three Cl ? anions in a distorted octahedral environment. The Cd metal centres are connected via Cl ? ligands, creating polymeric chains running along the a- axis direction. The conformation of the chains is stabilized by N—H...Cl hydrogen bonds.