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首页> 外文期刊>International Journal of Electrochemical Science >Study on Preparation and Performance of LiNi0.8Co0.1Mn0.1O2?as cathode materials for lithium ion batteries
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Study on Preparation and Performance of LiNi0.8Co0.1Mn0.1O2?as cathode materials for lithium ion batteries

机译:LINI0.8CO0.1MN0.1O2的制备和性能研究?作为锂离子电池的阴极材料

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Lithium ion battery has the advantages of high working voltage, good cycling performance andenvironmental friendliness. It is widely used in various battery energy storage devices. High nickelternary positive electrode materials with α-NaFeO2 type layered crystal structure have become the focusof research in recent years due to their high energy density and good cycling performance. In this paper,LiNi0.8Co0.1Mn0.1O2 high-nickel ternary material was prepared by hydrothermal method, and theproperties of the material were determined by phase analysis and electrochemical analysis. and theinfluence of sintering temperature on the morphology and structure and electrochemical performance ofthe ternary-type material was investigated. The results show that the optimal process conditions for theprecursor mixed lithium sintering are divided into two steps: the first step is calcined at 500°C for 6h,and the second step is calcined at 800°C for 8h. Under these conditions, the LiNi0.8Co0.1Mn0.1O2 has thebest morphology and the highest crystallinity, and has a specific capacity of 198.5 mAh·g-1at the rate of0.2 C. After 100 charge and discharge cycles at 0.2 C, the capacity retention rate is still 96.7%.
机译:锂离子电池的工作电压高的优点,循环性能良好的环境友好。它广泛用于各种电池储能设备。具有α-Nafeo2型层状晶体结构的高镍正极材料已成为近年来的重点,因为它们的高能量密度和良好的循环性能。本文采用水热法制料,采用水热法制备了LINI0.8CO0.1MN0.1O2高镍三元材料,并通过相分析和电化学分析确定了材料的优势。研究了烧结温度对三元型材料的形态和结构和电化学性能的影响。结果表明,将混合锂烧结的最佳过程条件分为两个步骤:第一步在500℃下煅烧6小时,第二步在800℃下煅烧8小时。在这些条件下,LINI0.8CO0.1MN0.1O2具有最佳的形态和最高结晶度,并且具有198.5mah·G-1AT的特定容量为0.2℃的速率。在0.2℃下100充电和放电循环后,产能保留率仍为96.7%。

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