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Alternative system to measure hydrogen content in molten aluminium using an electrochemical sensor

机译:使用电化学传感器测量熔融铝中氢含量的替代系统

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The most reliable techniques for the direct measurement of hydrogen content in liquid aluminium are based on Sievert’s law or use electrochemical probes introduced directly in liquid aluminium. The main drawback of these methods is the high cost of the equipment. An alternative apparatus has been developed and tested. This equipment combines a widely used and much cheaper hydrogen electrochemical sensor with the procedure already patented and commonly used by gas recirculation techniques. The device has been constructed and calibrated using gaseous mixtures of known hydrogen content. For validation, the results obtained with this apparatus have been compared with hydrogen content measurements in liquid aluminium using the commercial Alscan equipment in an industrial facility. Experimental results suggest that the apparatus proposed in this work is capable of detecting hydrogen content in liquid aluminium obtaining measurements that are in a good agreement with those obtained using the commercial Alscan equipment. On the other hand, results also suggest that it is important to take into account the operating atmospheric pressure to correct the readings obtained from Alscan when operating at atmospheric pressure levels far from 1 atm.
机译:直接测量液体铝中氢含量的最可靠的技术基于Sievert的定律或使用直接在液体铝中引入的电化学探针。这些方法的主要缺点是设备的高成本。已经开发并测试了替代装置。该设备将广泛使用和更便宜的氢电化学传感器与已经获得专利的程序和常用的气体再循环技术相结合。使用已知的氢含量的气态混合物构造和校准该装置。为了验证,使用工业设施中的商业Alscan设备在液体铝中与液体铝中获得的结果进行了比较。实验结果表明,本作作品中提出的装置能够检测液体铝中的氢含量,获得与使用商业ALSCAN设备获得的良好协议的测量值。另一方面,结果还表明,考虑到运行的大气压,以校正在远离1atm的大气压水平的大气压水平时从Alscan获得的读数。

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