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首页> 外文期刊>Atmospheric Measurement Techniques Discussions >The "Lung": a software-controlled air accumulator for quasi-continuous multi-point measurement of agricultural greenhouse gases
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The "Lung": a software-controlled air accumulator for quasi-continuous multi-point measurement of agricultural greenhouse gases

机译:“肺”:一种软件控制的空气蓄电池,用于准连续多点测量农业温室气体

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摘要

We describe the design and testing of a flexible bag ("Lung") accumulator attached to a gas chromatographic (GC) analyzer capable of measuring surface-atmosphere greenhouse gas exchange fluxes in a wide range of environmental/agricultural settings. In the design presented here, the Lung can collect up to three gas samples concurrently, each accumulated into a Tedlar bag over a period of 20 min or longer. Toggling collection between 2 sets of 3 bags enables quasi-continuous collection with sequential analysis and discarding of sample residues. The Lung thus provides a flexible "front end" collection system for interfacing to a GC or alternative analyzer and has been used in 2 main types of application. Firstly, it has been applied to micrometeorological assessment of paddock-scale N2O fluxes, discussed here. Secondly, it has been used for the automation of concurrent emission assessment from three sheep housed in metabolic crates with gas tracer addition and sampling multiplexed to a single GC. The Lung allows the same GC equipment used in laboratory discrete sample analysis to be deployed for continuous field measurement. Continuity of measurement enables spatially-averaged N2O fluxes in particular to be determined with greater accuracy, given the highly heterogeneous and episodic nature of N2O emissions. We present a detailed evaluation of the micrometeorological flux estimation alongside an independent tuneable diode laser system, reporting excellent agreement between flux estimates based on downwind vertical concentration differences. Whilst the current design is based around triplet bag sets, the basic design could be scaled up to a larger number of inlets or bags and less frequent analysis (longer accumulation times) where a greater number of sampling points are required.
机译:我们描述了一种柔性袋(“肺”)蓄能器的设计和测试,该蓄能器连接到气相色谱(GC)分析仪,该分析仪能够在各种环境/农业环境中测量表面大气温室气体交换通量。在此处呈现的设计中,肺可以同时收集到三个气体样品,每次在20分钟或更长时间累积到刺毛袋中。 2组3袋之间的切换集合使准连续收集能够顺序分析和丢弃样品残留物。因此,肺部提供了一种柔性“前端”收集系统,用于与GC或替代分析仪接口,并已用于2种主要应用类型。首先,它已经应用于围草级N2O助熔剂的微调评估,这里讨论。其次,它已被用于从储存在代谢板条箱中的三只羊的并发排放评估的自动化,所述气体示踪剂添加和采样复用到单个GC。肺允许在实验室离散样本分析中使用相同的GC设备进行连续现场测量。考虑到N2O排放的高度异质和情节性质,测量的连续性使得能够以更高的精度确定空间平均的N2O助熔剂。我们展示了与独立可调的二极管激光系统沿着独立可调的二极管激光系统的微观定理助焊剂估计的评估,基于下行垂直浓度差异报告磁通估计之间的优秀协议。虽然目前的设计基于三态袋组,但基本设计可以缩放到更大数量的入口或袋子,并且频繁的分析(更长的累积时间),其中需要更多的采样点。

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