Previous studies have shown that longwave (LW) spectral fluxes have unique merit in climate studies. Using Atmospheric Infrared Sounder (AIRS) radiances as a case study, this study presents an algorithm to derive the entire LW clear-sky spectral fluxes from spaceborne hyperspectral observations. No other auxiliary observations are needed in the algorithm. A clear-sky scene is identified using a three-step detection method. The identified clear-sky scenes are then categorized into different sub-scene types using information about precipitable water, lapse rate and surface temperature inferred from the AIRS radiances at six selected channels. A previously established algorithm is then used to invert AIRS radiances to spectral fluxes over the entire LW spectrum at 10?cm?1 spectral interval. Accuracy of the algorithms is evaluated against collocated Clouds and the Earth's Radiant Energy System (CERES) observations. For nadir-view observations, the mean difference between outgoing longwave radiation (OLR) derived by this algorithm and the collocated CERES OLR is 1.52?Wm?2 with a standard deviation of 2.46?Wm?2. When the algorithm is extended for viewing zenith angle up to 45°, the performance is comparable to that for nadir-view results.
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