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Validation of SCIAMACHY limb NO2 profiles using solar occultation measurements

机译:使用太阳掩星测量验证Sciamachy肢体No2型材

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The increasing amounts of reactive nitrogen in the stratosphere necessitate accurate global measurements of stratospheric nitrogen dioxide (NO2). Over the past decade, the SCIAMACHY (SCanning Imaging Absorption spectroMeter for Atmospheric CHartographY) instrument on ENVISAT (European Environmental Satellite) has been providing global coverage of stratospheric NO2 every 6 days. In this study, the vertical distributions of NO2 retrieved from SCIAMACHY limb measurements of the scattered solar light are validated by comparison with NO2 products from three different satellite instruments (SAGE II, HALOE and ACE-FTS). The retrieval algorithm based on the information operator approach is discussed, and the sensitivity of the SCIAMACHY NO2 limb retrievals is investigated. The photochemical corrections needed to make this validation feasible, and the chosen collocation criteria are described. For each instrument, a time period of two years is analyzed with several hundreds of collocation pairs for each year. As NO2 is highly variable, the comparisons are performed for five latitudinal bins and four seasons. In the 20 to 40 km altitude range, mean relative differences between SCIAMACHY and other instruments are found to be typically within 20 to 30%. The mean partial NO2 columns in this altitude range agree typically within 15% (both global monthly and zonal annual means). Larger differences are seen for SAGE II comparisons, which is consistent with the results presented by other authors. For SAGE II and ACE-FTS, the observed differences can be partially attributed to the diurnal effect error.
机译:平流层中的反应性氮的量增加需要精确的平坦氮二氧化氧化物的全局测量(NO2)。在过去的十年中,Envisat(欧​​洲环境卫星的大气图表)仪器(欧洲环境卫星)仪器的款式(扫描成像吸收光谱仪)每6天都提供全球平流层No2的覆盖范围。在这项研究中,通过与来自三种不同卫星仪器(Sage II,HALOE和ACE-FTS)的NO2产品进行比较,验证了从散射太阳灯的SCIMACHY LIMB测量中检索的NO 2的垂直分布。讨论了基于信息操作员方法的检索算法,研究了脚印No2肢体检索的灵敏度。使该验证可行所需的光化学校正以及所选择的搭配标准。对于每种仪器,每年用数百次搭配对分析两年的时间。由于NO2是高度变化的,对五个纬度箱和四季进行比较。在20至40公里的高度范围内,股主序结构和其他仪器之间的平均相对差异通常在20至30%以内。该高度范围内的平均部分NO2列通常在15%以内(全球每月和区年度手段)。 SAGE II比较看出较大的差异,这与其他作者呈现的结果一致。对于Sage II和ACE-FTS,观察到的差异可以部分地归因于昼夜效应误差。

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