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Lightning NOx emissions over the USA constrained by TES ozone observations and the GEOS-Chem model

机译:美国的闪电NOx排放由TES臭氧观测和地球化学模型约束

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Improved estimates of NOx from lightning sources are required to understand tropospheric NOx and ozone distributions, the oxidising capacity of the troposphere and corresponding feedbacks between chemistry and climate change. In this paper, we report new satellite ozone observations from the Tropospheric Emission Spectrometer (TES) instrument that can be used to test and constrain the parameterization of the lightning source of NOx in global models. Using the National Lightning Detection (NLDN) and the Long Range Lightning Detection Network (LRLDN) data as well as the HYPSLIT transport and dispersion model, we show that TES provides direct observations of ozone enhanced layers downwind of convective events over the USA in July 2006. We find that the GEOS-Chem global chemistry-transport model with a parameterization based on cloud top height, scaled regionally and monthly to OTD/LIS (Optical Transient Detector/Lightning Imaging Sensor) climatology, captures the ozone enhancements seen by TES. We show that the model's ability to reproduce the location of the enhancements is due to the fact that this model reproduces the pattern of the convective events occurrence on a daily basis during the summer of 2006 over the USA, even though it does not well represent the relative distribution of lightning intensities. However, this model with a value of 6 Tg N/yr for the lightning source (i.e.: with a mean production of 260 moles NO/Flash over the USA in summer) underestimates the intensities of the ozone enhancements seen by TES. By imposing a production of 520 moles NO/Flash for lightning occurring in midlatitudes, which better agrees with the values proposed by the most recent studies, we decrease the bias between TES and GEOS-Chem ozone over the USA in July 2006 by 40%. However, our conclusion on the strength of the lightning source of NOx is limited by the fact that the contribution from the stratosphere is underestimated in the GEOS-Chem simulations.
机译:从闪电源的估计,需要了解对流层NOx和臭氧分布,对流层的氧化能力以及化学与气候变化之间的相应反馈。在本文中,我们从对流层发射光谱仪(TES)仪器中报告了新的卫星臭氧观察,该仪器可用于测试和限制NOx的闪电源的参数化。使用全国雷电检测(NLDN)和长距离闪电检测网络(LRLDN)数据以及超级雷击运输和分散模型,我们表明TES在2006年7月在美国的对流事件下行的臭氧增强层的直接观察提供了直接观察。我们发现,基于云顶部高度的参数化的Geos-chem全球化学传输模型,以区域和每月缩放到OTD / LIS(光瞬态探测器/雷电成像传感器)气候学,捕获了TES所看到的臭氧增强功能。我们表明该模型再现增强位置的能力是由于该模型在2006年夏天在美国每天再现了对流事件的模式,即使它不太可能代表闪电强度的相对分布。然而,该模型具有6 Tg N / YR的闪电源(即,夏季美国260摩尔NO / Flash的平均生产)低估了TES所看到的臭氧增强的强度。通过施加520摩尔NO / Flash,在中期发生闪电,这更好地同意最近研究提出的价值,我们将在2006年7月在美国的TES和Geos-Chem臭氧之间的偏差减少40%。然而,我们对NOx的闪电源的强度的结论受到平流层的贡献在Geos-Chem模拟中受到影响。

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