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Exploiting stagnant conditions to derive robust emission ratio estimates for CO2, CO and volatile organic compounds in Paris

机译:利用停滞条件,以导出巴黎CO2,CO和挥发性有机化合物的稳健排放比估计

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We propose an approach to estimate urban emission ratios that takes advantage of the enhanced local urban signal in the atmosphere at low wind speed. We apply it to estimate monthly ratios between CO2, CO and some VOCs from several atmospheric concentration measurement datasets acquired in the centre of Paris between 2010 and 2014. We find that this approach is not very sensitive to the regional background level definition and that, in the case of Paris, it samples all days (weekdays and weekends) and all hours of the day evenly. A large seasonal variability of the ΔCO?∕?ΔCO2 ratio in Paris is shown, with a difference of around 60?% between the extreme values and a strong anti-correlation (r2?=?0.75) with atmospheric temperature. The comparison of the ratios obtained for two short measurement campaigns conducted in two different districts and two different periods (autumn and winter) shows differences ranging from ?120 to +63?%. A comparison with a highly resolved regional emission inventory suggests some spatial variations of the ratio within the city.
机译:我们提出了一种方法来估计城市排放比率,以利用低风速下的大气中增强的本地城市信号。我们将其应用于2010年至2010年间巴黎中心收购的几种大气浓度测量数据集的CO2,CO和一些VOC之间的月度比率。我们发现这种方法对区域背景水平定义并不是很敏感,而且巴黎的案例,它样本所有的日子(平日和周末)和一天中的所有时间均匀。显示了巴黎ΔCo的大季节性变异性,在极值和具有大气温度的极值和强抗相关之间的差异约为60Ω%。在两个不同地区和两个不同时期进行的两个短测量运动获得的比率比较,显示出从Δ20至+63?%的差异。与高度解决的区域排放库存的比较表明了城市内比率的一些空间变化。

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