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Diurnal, seasonal and long-term variations of global formaldehyde columns inferred from combined OMI and GOME-2 observations

机译:从omi和Gome-2观察组合推断的全球甲醛柱的昼夜,季节和长期变化

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We present the new version (v14) of the BIRA-IASB algorithm for the retrieval of formaldehyde (H2CO) columns from spaceborne UV–visible sensors. Applied to OMI measurements from Aura and to GOME-2 measurements from MetOp-A and MetOp-B, this algorithm is used to produce global distributions of H2CO representative of mid-morning and early afternoon conditions. Its main features include (1) a new iterative DOAS scheme involving three fitting intervals to better account for the O2–O2 absorption, (2) the use of earthshine radiances averaged in the equatorial Pacific as reference spectra, and (3) a destriping correction and background normalisation resolved in the across-swath position. For the air mass factor calculation, a priori vertical profiles calculated by the IMAGES chemistry transport model at 09:30 and 13:30 LT are used. Although the resulting GOME-2 and OMI H2CO vertical columns are found to be highly correlated, some systematic differences are observed. Afternoon columns are generally larger than morning ones, especially in mid-latitude regions. In contrast, over tropical rainforests, morning H2CO columns significantly exceed those observed in the afternoon. These differences are discussed in terms of the H2CO column variation between mid-morning and early afternoon, using ground-based MAX-DOAS measurements available from seven stations in Europe, China and Africa. Validation results confirm the capacity of the combined satellite measurements to resolve diurnal variations in H2CO columns. Furthermore, vertical profiles derived from MAX-DOAS measurements in the Beijing area and in Bujumbura are used for a more detailed validation exercise. In both regions, we find an agreement better than 15 % when MAX-DOAS profiles are used as a priori for the satellite retrievals. Finally, regional trends in H2CO columns are estimated for the 2004–2014 period using SCIAMACHY and GOME-2 data for morning conditions, and OMI for early afternoon conditions. Consistent features are observed, such as an increase of the columns in India and central–eastern China, and a decrease in the eastern US and Europe. We find that the higher horizontal resolution of OMI combined with a better sampling and a more favourable illumination at midday allow for more significant trend estimates, especially over Europe and North America. Importantly, in some parts of the Amazonian forest, we observe with both time series a significant downward trend in H2CO columns, spatially correlated with areas affected by deforestation.
机译:我们介绍了Bira-IASB算法的新版本(V14),用于从星载UV可见传感器中检索甲醛(H2CO)柱的算法。从Aura和Metop-A和MetoP-B的Gome-2测量应用于OMI测量,该算法用于产生中午和早期条件的全球H2CO代表的全局分布。其主要特点包括(1)一种新的迭代DOAS方案,涉及三个拟合间隔,更好地占O2-O2吸收,(2)在赤道太平洋作为参考光谱中使用土水辐射,以及(3)腐蚀校正背景规范化在跨越垃圾邮件位置解决。对于空气质量因子计算,使用图像化学传输模型在09:30和13:30下计算的先验垂直曲线。尽管发现所得到的Gome-2和OMI H2CO垂直柱具有高度相关性,但观察到一些系统差异。下午柱通常比早晨的柱子大,尤其是中纬度地区。相比之下,在热带雨林上,早晨的H2CO柱明显超过下午观察到的柱。这些差异在于中午和午后之间的H2Co柱变化,使用欧洲,中国和非洲的七个站点提供的基于地基的MAX-DOA测量。验证结果证实了组合卫星测量的容量,以解决H2CO列中的昼夜变化。此外,源自北京地区和Bujumbura的Max-Doas测量衍生的垂直型材用于更详细的验证练习。在这两个地区,当Max-DoaS配置文件用作卫星检索的先验时,我们发现一个比15%更好的协议。最后,使用Sciamachy和Gome-2数据的2004 - 2014年早晨条件和众多下午条件的OMI估计H2CO专栏的区域趋势。观察到一致的特征,例如印度和中国中央东部的柱子的增加,以及美国东部和欧洲的减少。我们发现OMI的较高水平分辨率与午间更好的采样和更有利的照明允许更加重要的趋势估计,特别是在欧洲和北美。重要的是,在亚马逊森林的某些地区,我们观察到H2CO列中的时间序列,与受森林影响影响的地区有关的显着下降趋势。
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