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Validation of satellite formaldehyde (HCHO) retrievals using observations from 12 aircraft campaigns

机译:使用12架飞机运动的观察验证卫星甲醛(HCHO)检索

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Formaldehyde (HCHO) has been measured from space for more than 2 decades. Owing to its short atmospheric lifetime, satellite HCHO data are used widely as a proxy of volatile organic compounds (VOCs; please refer to Appendix A for abbreviations and acronyms), providing constraints on underlying emissions and chemistry. However, satellite HCHO products from different satellite sensors using different algorithms have received little validation so far. The accuracy and consistency of HCHO retrievals remain largely unclear. Here we develop a validation platform for satellite HCHO retrievals using in situ observations from 12 aircraft campaigns with a chemical transport model (GEOS-Chem) as the intercomparison method. Application to the NASA operational OMI HCHO product indicates negative biases (?44.5% to ?21.7%) under high-HCHO conditions, while it indicates high biases (+66.1% to +112.1%) under low-HCHO conditions. Under both conditions, HCHO a priori vertical profiles are likely not the main driver of the biases. By providing quick assessment of systematic biases in satellite products over large domains, the platform facilitates, in an iterative process, optimization of retrieval settings and the minimization of retrieval biases. It is also complementary to localized validation efforts based on ground observations and aircraft spirals.
机译:甲醛(HCHO)已经从空间衡量超过2年。由于其短大气寿命,卫星HCHO数据被广泛使用作为挥发性有机化合物的代理(VOCS;请参阅附录A用于缩写和首字母缩略词),为底层排放和化学提供限制。然而,到目前为止,来自不同卫星传感器的卫星HCHO产品已经收到了几乎没有验证的验证。 Hcho检索的准确性和一致性仍然很大程度上不清楚。在这里,我们为卫星HCHO检索开发了验证平台,使用来自12架飞机运动的原位观察,其中12架飞机与化学传输模型(Geos-Chem)作为相互作用的方法。在NASA操作OMI HCHO产物中的应用表明在高HCHO条件下的负偏差(α4.5%至21.7%),而在低HCHO条件下表明它在低HCHO条件下偏差高(+ 66.1%至+ 112.1%)。在两个条件下,HCHO先验垂直轮廓可能不是偏差的主要驱动器。通过在大型域中提供对卫星产品的系统偏差的快速评估,平台在迭代过程中促进了检索设置的优化和检索偏差的最小化。它还根据基于地面观测和飞机螺旋的本地化验证工作互补。
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