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New particle formation and sub-10nm size distribution measurements during the A-LIFE field experiment in Paphos, Cyprus

机译:塞浦路斯帕福斯的A-Life Field实验期间的新粒子形成和亚10nm尺寸分布测量

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Atmospheric particle size distributions were measured in Paphos, Cyprus, during the A-LIFE (absorbing aerosol layers in a changing climate: ageing, lifetime and dynamics) field experiment from 3 to 30?April?2017. The newly developed differential mobility analyser train (DMA-train) was deployed for the first time in an atmospheric environment for the direct measurement of the nucleation mode size range between 1.8 and 10nm diameter. The DMA-train set-up consists of seven size channels, of which five are set to fixed particle mobility diameters and two additional diameters are obtained by alternating voltage settings in one DMA every 10s. In combination with a conventional mobility particle size spectrometer (MPSS) and an aerodynamic particle sizer (APS) the complete atmospheric aerosol size distribution from 1.8nm to 10μm was covered. The focus of the A-LIFE study was to characterize new particle formation (NPF) in the eastern Mediterranean region at a measurement site with strong local pollution sources. The nearby Paphos airport was found to be a large emission source for nucleation mode particles, and we analysed the size distribution of the airport emission plumes at approximately 500m from the main runway. The analysis yielded nine NPF events in 27 measurement days from the combined analysis of the DMA-train, MPSS and trace gas monitors. Growth rate calculations were performed, and a size dependency of the initial growth rate (10nm) was observed for one event case. Fast changes of the sub-10nm size distribution on a timescale of a few minutes were captured by the DMA-train measurement during early particle growth and are discussed in a second event case. In two cases, particle formation and growth were detected in the nucleation mode size range which did not exceed the 10nm threshold. This finding implies that NPF likely occurs more frequently than estimated from studies where the lower nanometre size regime is not covered by the size distribution measurements.
机译:在A-Life(在变化气候中吸收气溶胶层的帕斯斯(吸收气溶胶层)的帕福斯测量大气粒径分布:衰老,寿命和动态)田间实验从3到30?2017年4月?新开发的差动移动性分析仪火车(DMA-Train)在大气环境中首次部署,以直接测量直径1.8至10nm之间的成核模式尺寸范围。 DMA-Train设置由七个尺寸通道组成,其中五个被设置为固定粒子迁移率直径,并且通过每10次的一个DMA中的电压设置获得两个额外的直径。结合常规的迁移率粒度光谱仪(MPS)和空气动力学粒子Sizer(APS),覆盖了1.8nm至10μm的完整大气气溶胶尺寸分布。 A-Life研究的重点是在具有强大当地污染源的测量部位的东部地中海地区的新粒子形成(NPF)。附近的帕福斯机场被发现是成核模式颗粒的大型排放源,我们分析了机场排放羽毛的大约500米从主跑道的尺寸分布。从DMA火车,MPSS和痕量气体监测器的组合分析,分析在27个测量天中产生了九种NPF事件。进行生长速率计算,并观察到一个事件案例的初始生长速率(10nm)的尺寸依赖性。在早期粒子生长期间的DMA列车测量捕获了几分钟的秒10nm尺寸分布的快速变化,并且在第二次事件情况下讨论。在两种情况下,在核切割模式尺寸范围内检测到不超过10nm阈值的颗粒形成和生长。该发现意味着NPF可能比从下纳米尺寸制度没有被尺寸分布测量覆盖的研究更频繁地发生。

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