Quantifying the emission changes and associated air quality impacts during the COVID-19 pandemic on the North China Plain: a response modeling study

摘要

Quantification of emission changes is a prerequisite for the assessment of control effectiveness in improving air quality. However, the traditional bottom-up method for characterizing emissions requires detailed investigation of emissions data (e.g., activity and other emission parameters) that usually takes months to perform and limits timely assessments. Here we propose a novel method to address this issue by using a response model that provides real-time estimation of emission changes based on air quality observations in combination with emission-concentration response functions derived from chemical transport modeling. We applied the new method to quantify the emission changes on the North China Plain (NCP) due to the COVID-19 pandemic shutdown, which overlapped the Spring Festival (also known as Chinese New Year) holiday. Results suggest that the anthropogenic emissions of NO2, SO2, volatile organic compound (VOC) and primary PM2.5 on the NCP were reduced by 51%, 28%, 67% and 63%, respectively, due to the COVID-19 shutdown, indicating longer and stronger shutdown effects in 2020 compared to the previous Spring Festival holiday. The reductions of VOC and primary PM2.5 emissions are generally effective in reducing O3 and PM2.5 concentrations. However, such air quality improvements are largely offset by reductions in NOx emissions. NOx emission reductions lead to increases in O3 and PM2.5 concentrations on the NCP due to the strongly VOC-limited conditions in winter. A strong NH3-rich condition is also suggested from the air quality response to the substantial NOx emission reduction. Well-designed control strategies are recommended based on the air quality response associated with the unexpected emission changes during the COVID-19 period. In addition, our results demonstrate that the new response-based inversion model can well capture emission changes based on variations in ambient concentrations and thereby illustrate the great potential for improving the accuracy and efficiency of bottom-up emission inventory methods.