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Source apportionment of atmospheric mercury in the remote marine atmosphere: Mace Head GAW station, Irish western coast

机译:偏远海洋氛围中大气汞的源头分摊:Mace Head Gaw Station,爱尔兰西海岸

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We examined recent atmospheric mercury concentrations measured with a?high temporal resolution of 15min at Mace Head, a?GAW station on the western coast of Ireland. We attributed a?direct contribution of 34% (0.44ng?m?3) to primary sources. Additionally, a?steep decline (0.05ng?yr?1) in mercury concentrations was observed between 2013 and 2018. Using a?stereo algorithm we reconstructed 99.9% of the atmospheric mercury. A?conservative analysis demonstrated no decrease in total gaseous mercury (TGM) associated with atmospheric species typically used as tracers for oceanic emissions. The results show that the atmospheric mercury mass is mainly loaded in a?baseline factor with an ongoing decline. Moreover, we exploit temporal variation and wind pattern effects in the measured atmospheric species; the results show that the diurnal variation and seasonality in TGM observed in Mace Head are closely related to other species linked to primary sources and can be explained by transport from continental areas.
机译:我们检查了最近在爱尔兰西海岸的术士头部的15分钟内测量的大气汞浓度,在术士头部的15分钟内测量。我们将34%(0.44ng?m≤3)的直接贡献给主要来源。另外,在2013和2018之间观察到汞浓度的陡峭下降(0.05ng?1)。使用a?立体声算法,我们重建了99.9%的大气汞。 a?保守分析表明,与通常用作海洋排放的示踪剂的大气种类相关的总气体汞(TGM)的降低。结果表明,大气汞肿块主要装载在一个持续下降的基线因素中。此外,我们利用了测量的大气种类中的时间变化和风模式效应;结果表明,术术头部观察到的TGM中的昼夜变异和季节性与与主要来源相关的其他物种密切相关,可以通过大陆地区的运输来解释。

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