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Long-term variations in ozone levels in the troposphere and lower stratosphere over Beijing: observations and model simulations

机译:对流层臭氧水平的长期变化,对流层和北京较低的平流层:观测和模型模拟

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Tropospheric ozone is both a major pollutant and a short-lived greenhouse gas and has therefore caused much concern in recent years. The ozone profile in the troposphere and lower stratosphere over Beijing has been observed since 2002 by ozonesondes developed by the Institute of Atmospheric Physics. Increasing concentrations of tropospheric ozone from 2002 to 2010 measured by these balloon-based observations have been reported previously. As more observations are now available, we used these data to analyse the long-term variability of ozone over Beijing during the whole period from 2002 to 2018. The ozonesondes measured increasing concentrations of ozone from 2002 to 2012 in both the troposphere and lower stratosphere. There was a sudden decrease in observed ozone between 2011 and 2012. After this decrease, the increasing trend in ozone concentrations slowed down, especially in the mid-troposphere, where the positive trend became neutral. We used the Chemical Lagrangian Model of the Stratosphere (CLaMS) to determine the influence of the transport of ozone from the stratosphere to the troposphere on the observed ozone profiles. CLaMS showed a weak increase in the contribution of stratospheric ozone before the decrease in 2011–2012 and a much more pronounced decrease after this time. Because there is no tropospheric chemistry in CLaMS, the sudden decrease simulated by CLaMS indicates that a smaller downward transport of ozone from the stratosphere after 2012 may explain a significant part of the observed decrease in ozone in the mid-troposphere and lower stratosphere. However, the influence of stratospheric ozone in the lower troposphere is negligible in CLaMS, and the hiatus in the positive trend after 2012 can be attributed to a reduction in ozone precursors as a result of stronger pollution control measures in Beijing.
机译:对流层臭氧既是主要污染物和短寿命温室气体,因此在近几年引起了很大的关注。在对流层中的臭氧分布和较低的平流层北京已经通过大气物理研究所研制臭氧探空仪自2002年以来观测到。 2002至10年由这些基于气球观测测量对流层臭氧浓度的增加已有报道。随着越来越多的意见是现在可用,我们使用这些数据来分析整个期间从2002年至2018年在臭氧北京的长期变化测量在对流层及平流层下部都增加臭氧浓度的2002年至2012年的臭氧探空仪。有在2011年和2012年间观测到臭氧这种下降后突然降低,在臭氧浓度增加的趋势放缓,尤其是在中对流层,其中的积极趋势呈中性。我们所使用的平流层(蛤)的化学拉格朗日模型,以确定臭氧从同温层上所观察到的臭氧轮廓的对流层的传输的影响。蛤蜊显示,平流层臭氧在2011 - 2012年的下降,在此时间后更加明显降低之前的贡献微弱增长。因为在蛤没有对流层化学,由蛤模拟的突然降低,表明臭氧从平流层在2012年后更小的下行传输可以解释在对流层中部臭氧观测到下降的显著部分与下部平流层。然而,平流层臭氧在对流层低层的影响是微不足道的蛤,并在2012年后的积极趋势裂孔可以归因于臭氧前体减少为北京强污染控制措施的结果。

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