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Spatio-temporal variations of nitric acid total columns from 9 years of IASI measurements – a driver study

机译:9年IASI测量的硝酸总柱的时空变化 - 驾驶员研究

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This study aims to understand the spatial and temporal variability of HNO3 total columns in terms of explanatory variables. To achieve this, multiple linear regressions are used to fit satellite-derived time series of HNO3 daily averaged total columns. First, an analysis of the IASI 9-year time series (2008–2016) is conducted based on various equivalent latitude bands. The strong and systematic denitrification of the southern polar stratosphere is observed very clearly. It is also possible to distinguish, within the polar vortex, three regions which are differently affected by the denitrification. Three exceptional denitrification episodes in 2011, 2014 and 2016 are also observed in the Northern Hemisphere, due to unusually low arctic temperatures. The time series are then fitted by multivariate regressions to identify what variables are responsible for HNO3 variability in global distributions and time series, and to quantify their respective influence. Out of an ensemble of proxies (annual cycle, solar flux, quasi-biennial oscillation, multivariate ENSO index, Arctic and Antarctic oscillations and volume of polar stratospheric clouds), only the those defined as significant (p value0.05) by a selection algorithm are retained for each equivalent latitude band. Overall, the regression gives a good representation of HNO3 variability, with especially good results at high latitudes (60–80% of the observed variability explained by the model). The regressions show the dominance of annual variability in all latitudinal bands, which is related to specific chemistry and dynamics depending on the latitudes. We find that the polar stratospheric clouds (PSCs) also have a major influence in the polar regions, and that their inclusion in the model improves the correlation coefficients and the residuals. However, there is still a relatively large portion of HNO3 variability that remains unexplained by the model, especially in the intertropical regions, where factors not included in the regression model (such as vegetation fires or lightning) may be at play.
机译:本研究旨在了解在解释变量方面的HNO3总列的空间和时间变异性。为实现这一点,使用多元线性回归来配合HNO3日常总柱的卫星衍生的时间序列。首先,基于各种等效纬度频带进行IASI 9年级时间序列(2008-2016)的分析。非常清楚地观察到南极平流层的强大和系统的脱氮。还可以区分,在极性涡旋中,三个区域不同地受反硝化影响。在北半球也观察到2011年的三个特殊的脱氮集,由于异常低的北极气温,北半球也观察到。然后,时间序列被多变量回归安装,以确定全局分布和时间序列中的HNO3变异性的变量以及量化各自的影响。出代理的集合(年度周期,太阳能通量,准二年级振荡,多变量ENSO指数,北极和南极振荡和极地平流层云的体积),仅通过选择算法定义为重要(P值0.05)的那些保留每个等效纬度频段。总的来说,回归给出了HNO3变异性的良好代表性,在高纬度的效果特别良好(60-80%的观察到可变异的60%)。回归展示了所有纬度频段的年度变异性的主导地位,这与根据纬度的特定化学和动力学相关。我们发现极地平流层云(PSC)在极地区域也具有重大影响,并且它们在模型中的包含改善了相关系数和残差。然而,仍然存在相对大的HNO3变异性,其模型仍然是未解释的,尤其是在闭间区域中,其中不包括在回归模型(例如植被火灾或闪电)中的因素可能处于游戏中。

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