Sensitivity of a global model to the uptake of N2O5 by tropospheric aerosol

摘要

The uptake of N2O5 on aerosol impacts atmospheric concentrations of NOx and so O3, OH, and hence CH4. Laboratory studies show significant variation in the rate of uptake, with a general decline in the value of N2O5 over the last decade as increasingly relevant tropospheric proxies have been studied. In order to understand the implication of this decline for tropospheric composition, a global model of tropospheric chemistry and transport (GEOS-Chem) is run with differing values of N2O5 (0.0, 10106, 10104, 10?3, 5103, 10?2, 210102, 0.1, 0.2, 0.5, and 1.0). We identify three regimes in the model response. At low values of N2O5, the model shows reduced sensitivity to the value of N2O5 as heterogeneous uptake of N2O5 does not provide a significant pathway to perturb NOx burdens. At high values of N2O5 the model again shows reduced sensitivity to the value of N2O5, as NOx loss through heterogeneous removal of N2O5 is limited by the rate of production of NO3, rather than the rate of heterogeneous uptake. At intermediate values of N2O5 the model shows significant sensitivity to the value of N2O5. We find regional differences in the model's response to changing N2O5. Regions with high aerosol surface area and low temperatures show NO3 production becoming rate limiting at lower N2O5 values than regions with lower aerosol surface area and higher temperatures. The northern extra-tropics show significant sensitivity to the value of N2O5 at values consistent with current literature (0.001–0.02), thus an accurate description of N2O5 is required for adequate simulation of O3 burdens and long-range transport of pollutants in this region. Our model simulations also provide insight into the sensitivity of coupled chemistry-aerosol simulations to the choice of N2O5. We find little change in the global sensitivity of NOx, O3 and OH to N2O5 in the range 0.05 to 1.0, but a significant drop in sensitivity below this range. Thus simulations of the coupled impact of both chemistry and aerosol changes through time will be sensitive to the choice of N2O5.