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Mineralogy and geochemistry of Asian dust: dependence on migration path, fractionation, and reactions with polluted air

机译:亚洲粉尘的矿物学和地球化学:依赖迁移路径,分级和污染空气的反应

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Mineralogical and geochemical data are essential for estimating the effects of long-range transport of Asian dust on the atmosphere, biosphere, cryosphere, and pedosphere. However, consistent long-term data sets of dust samples are rare. This study analyzed 25 samples collected during 14 Asian dust events occurring between 2005 and 2018 on the Korean Peninsula and compared them to 34 soil samples (20μm) obtained from the Mongolian Gobi Desert, which is a major source of Asian dust. The mineralogical and geochemical characteristics of Asian dust were consistent with those of fine source soils in general. In dust, clay minerals were most abundant, followed by quartz, plagioclase, K-feldspar, calcite, and gypsum. The trace element contents were influenced by the mixing of dust with polluted air and the fractionation of rare earth elements. Time-series analyses of the geochemical data of dust, combined with satellite remote sensing images, showed a significant increase in the Ca content in the dust crossing the Chinese Loess Plateau and the sandy deserts of northern China. Calcareous sediments in the sandy deserts and pedogenic calcite-rich loess are probable sources of additional Ca. Dust-laden air migrating toward Korea mixes with polluted air over East Asia. Gypsum, a minor mineral in source soils, was formed by the reaction between calcite and pollutants. This study describes not only the representative properties of Asian dust but also their variation according to the migration path, fractionation, and atmospheric reactions.
机译:矿物学和地球化学数据对于估计亚洲粉尘远程运输对大气,生物圈,冰屋和踏板的影响至关重要。然而,一致的长期数据集灰尘样本是罕见的。本研究分析了在2005年至2018年的14个亚洲尘埃事件中收集的25个样本,并将其与蒙古戈壁沙漠中获得的34种土壤样品(20μm)进行比较,这是亚洲尘埃的主要来源。亚洲粉尘的矿物学和地球化学特征与一般细源土壤的矿物质学和地球化学特征一致。在灰尘中,粘土矿物质最丰富,其次是石英,Plagioclase,K-Feldspar,方解石和石膏。微量元素内容物受到污染空气的混合和稀土元素的分馏的影响。与卫星遥感图像相结合的灰尘地球化学数据的时间序列分析表现出中国黄土高原和中国北方沙漠的粉尘中的CA含量显着增加。含沙沙漠和富有的石油富含黄土的钙质沉积物是额外的含量的可能性。覆盖韩国的灰尘空气与东亚的污染空气混合。通过方解石和污染物之间的反应形成石膏,源土壤中的次要矿物质。本研究不仅描述了亚洲粉尘的代表性,而且描述了它们根据迁移路径,分馏和大气反应的变化。

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