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首页> 外文期刊>Atmospheric Chemistry and Physics Discussions >Inter-annual variability of surface ozone at coastal (Dumont d'Urville,2004–2014) and inland (Concordia, 2007–2014) sites in East Antarctica
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Inter-annual variability of surface ozone at coastal (Dumont d'Urville,2004–2014) and inland (Concordia, 2007–2014) sites in East Antarctica

机译:沿海地面臭氧的年度欧洲臭氧(Dumont D'Urville,2004-2014)和内陆(Concordia,2007-2014)站在东南南极洲的跨年变异性

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Surface ozone has been measured since 2004 at the coastal East Antarctic site of Dumont d'Urville (DDU), and since 2007 at the Concordia station located on the high East Antarctic plateau. This paper discusses long-term changes, seasonal and diurnal cycles, as well as inter-annual summer variability observed at these two East Antarctic sites. At Concordia, near-surface ozone data were complemented by balloon soundings and compared to similar measurements done at the South Pole. The DDU record is compared to those obtained at the coastal site of Syowa, also located in East Antarctica, as well as the coastal sites of Neumayer and Halley, both located on the coast of the Weddell Sea in West Antarctica. Surface ozone mixing ratios exhibit very similar seasonal cycles at Concordia and the South Pole. However, in summer the diurnal cycle of ozone is different at the two sites with a drop of ozone in the afternoon at Concordia but not at the South Pole. The vertical distribution of ozone above the snow surface also differs. When present, the ozone-rich layer located near the ground is better mixed and deeper at Concordia (up to 400?m) than at the South Pole during sunlight hours. These differences are related to different solar radiation and wind regimes encountered at these two inland sites. DDU appears to be the coastal site where the impact of the late winter/spring bromine chemistry is the weakest, but where the impact of elevated ozone levels caused by NOx snow emissions from the high Antarctic plateau is the highest. The highest impact of the bromine chemistry is seen at Halley and Neumayer, and to a lesser extent at Syowa. These three sites are only weakly impacted by the NOx chemistry and the net ozone production occurring on the high Antarctic plateau. The differences in late winter/spring are attributed to the abundance of sea ice offshore from the sites, whereas those in summer are related to the topography of East Antarctica that promotes the katabatic flow bringing oxidant-rich inland air masses to the site. There appears to be a decreasing change in summer surface ozone at the two East Antarctic sites of Concordia and DDU over the most recent period (2004–2014 and 2007–2014). Further research, including continued monitoring, is needed at these two sites to better separate the effect of synoptic transport from possible change of NOx snow emissions in response to recovery of the stratospheric ozone layer leading to penetration of more UV radiation to the surface.
机译:自2004年以来,在杜蒙德·乌尔维尔(DDU)的沿海东南南极部位以来,已经测量了表面臭氧,自2007年以来,位于高东南南极高原的Concordia站。本文讨论了长期变化,季节性和昼夜循环,以及在这两个东南南极地点观察到的年度夏季变异性。在Concordia,近表面臭氧数据被球囊探测互补,与南极所做的相似测量相比。将DDU记录与Syowa沿海地区获得的记录相比,也位于东南极洲的东部,以及位于西南极洲的Weddell海的海岸的Neumayer和Halley的沿海地区。表面臭氧混合比率在Concordia和南极展出非常相似的季节性循环。然而,在夏天,臭氧的昼夜循环在两个地点不同,午后在Concordia下午臭氧,但不在南极。雪地表面上方臭氧的垂直分布也不同。当存在时,富含臭氧层的层位于地面附近,在阳光小时内比南极更好地混合和更深的康乐士(最多400米)。这些差异与在这两个内陆地点遇到的不同的太阳辐射和风制度有关。 DDU似乎是沿海网站,晚冬季/春季溴化学的影响是最弱的,但在高南极高原的NOx雪地排放引起的臭氧水平的影响最高。溴化溴化学的最高影响是在哈雷和Neumayer中看到的,并在Syowa的较小程度上看到。这三个地点仅受到NOx化学和高南极高原发生的净臭氧生产弱影响。冬季/春季的差异归因于遗址的海上海冰的丰富,而那些在夏季的海上冰冰与东南极洲的地形有关,促进了将富含氧化的内陆空气群体带到现场的Katabatic流程。在最近一段时间(2004-2014和2007-2014),在Concordia和DDU的两位东南南极地点夏表面臭氧的变化似乎有所下降。在这两个地点需要进一步的研究,包括持续的监测,以更好地将概要运输的效果从NOx散热层的可能变化中分开,以响应分流层臭氧层的恢复导致渗透到表面的渗透。

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