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First long-term study of particle number size distributions and new particle formation events of regional aerosol in the North China Plain

机译:北方平原区域气溶胶颗粒数尺寸分布和新粒子形成事件的首次研究

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Atmospheric particle number size distributions (size range 0.003–10 μm) were measured between March 2008 and August 2009 at Shangdianzi (SDZ), a rural research station in the North China Plain. These measurements were made in an attempt to better characterize the tropospheric background aerosol in Northern China. The mean particle number concentrations of the total particle, as well as the nucleation, Aitken, accumulation and coarse mode were determined to be 1.2 ± 0.9 104, 3.6 ± 7.9 103, 4.4 ± 3.4 103, 3.5 ± 2.8 103 and 2 ± 3 cm3, respectively. A general finding was that the particle number concentration was higher during spring compared to the other seasons. The air mass origin had an important effect on the particle number concentration and new particle formation events. Air masses from northwest (i.e. inner Asia) favored the new particle formation events, while air masses from southeast showed the highest particle mass concentration. Significant diurnal variations in particle number were observed, which could be linked to new particle formation events, i.e. gas-to-particle conversion. During particle formation events, the number concentration of the nucleation mode rose up to maximum value of 104 cm3. New particle formation events were observed on 36% of the effective measurement days. The formation rate ranged from 0.7 to 72.7 cm3 s1, with a mean value of 8.0 cm?3 s?1. The value of the nucleation mode growth rate was in the range of 0.3–14.5 nm h1, with a mean value of 4.3 nm h?1. It was an essential observation that on many occasions the nucleation mode was able to grow into the size of cloud condensation nuclei (CCN) within a matter of several hours. Furthermore, the new particle formation was regularly followed by a measurable increase in particle mass concentration and extinction coefficient, indicative of a high abundance of condensable vapors in the atmosphere under study.
机译:2008年3月至2009年3月,在华北平原农村研究站,在2008年3月和2009年8月之间测量了大气粒子数尺寸分布(大小范围0.003-10μm)。这些测量是为了更好地表征北方的对流层背景气溶胶。总颗粒的平均颗粒数浓度以及核切割,α1,积累和粗糙模式确定为1.2±0.9 104,3.6±7.9 103,4.4±3.4 103,3.5±2.8 103和2±3 cm3 , 分别。一般发现是,与其他季节相比,春季粒子浓度较高。空气质量源对颗粒数浓度和新的颗粒形成事件具有重要作用。来自西北部的空气群众(即内部亚洲)赞成新的粒子形成赛事,而东南部的空气质量呈现最高的粒子质量浓度。观察到颗粒数的显着差异,其可以与新的颗粒形成事件相关联,即气于颗粒转化。在颗粒形成事件期间,成核模式的数量浓度升至最大值104cm 3。在有效测量天的36%上观察到新的颗粒形成事件。形成速率范围为0.7至72.7cm 3 S1,平均值为8.0cm≤3s≤1。成核模式生长速率的值在0.3-14.5nm H1的范围内,平均值为4.3nm H 2。这是一个重要的观察,即在几个小时内,在许多情况下,成核模式能够在云凝结核(CCN)的大小程度上。此外,通常定期进行新的颗粒形成,然后测量颗粒质量浓度和消光系数的可测量增加,这表明在研究中的大气中的高度可粘稠的蒸气。

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