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Satellite observations of long range transport of a large BrO plume in the Arctic

机译:北极大型兄弟羽毛远程运输的卫星观察

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Ozone Depletion Events (ODE) during polar springtime are a well known phenomenon in the Arctic and Antarctic boundary layer. They are caused by the catalytic destruction of ozone by halogens producing reactive halogen oxides like bromine monoxide (BrO). The key halogen bromine can be rapidly transferred into the gas phase in an autocatalytic process – the so called "Bromine Explosion". However, the exact mechanism, which leads to an initial bromine release as well as the influence of transport and chemical processes on BrO, is still not clearly understood. In this study, BrO measurements from the satellite instrument GOME-2 are used together with model calculations with the dispersion model FLEXPART to study an arctic BrO event in March 2007, which could be tracked over several days and a large area. Full BrO activation was observed within one day east of Siberia with subsequent transport to Hudson Bay. The event was linked to a cyclone with very high surface wind speeds, which could have been involved in the production and lifting of aerosols or blowing snow. Considering the short life time of BrO, transported aerosols or snow can also provide the surface for BrO recycling within the plume for several days. The evolution of the BrO plume could be reproduced by FLEXPART simulations of a passive tracer indicating that the activated air mass was transported all the way from Siberia to Hudson Bay. To localise the most probable transport height, model runs initialised in different heights have been performed showing similar transport patterns throughout the troposphere but best agreement with the measurements between the surface and 3 km. The influence of changes in tropopause height on measured BrO values has been considered, but cannot completely explain the observed high BrO values. Backward trajectories from the area of BrO initialisation show upward lifting from the surface up to 3 km and no indication for intrusion of stratospheric air. These observations are consistent with a scenario in which bromine in the air mass was activated on the surface within the cyclone, lifted upwards and transported over several thousand kilometres to Hudson Bay.
机译:极性春天期间的臭氧耗尽事件(ode)是北极和南极边界层中已知的现象。它们是由卤素生产反应性卤素氧化物(如溴一氧化物(兄弟))催化破坏臭氧引起的。关键卤素溴可以在自催化过程中快速转移到气相中 - 所谓的“溴爆炸”所谓的“溴爆炸”。然而,仍然没有清楚地理解导致初始溴释放的确切机制以及运输和化学过程对兄弟的影响。在这项研究中,卫星仪器Gome-2的兄弟测量与分散模型Flexpart一起使用的模型计算,以便在2007年3月的北极兄弟赛事中研究,这可以在几天内跟踪,大面积。在西伯利亚以东的一天内观察到全面的兄弟激活,随后运输到哈德森湾。该事件与具有非常高的表面风速的旋风有关,这可能参与了气溶胶或吹雪的生产和提升。考虑到兄弟的短暂寿命,运输的气溶胶或雪也可以为表面提供几天内的兄弟再循环。可以通过无源示踪剂的Flexpart模拟来再现兄弟羽流的演变,该模拟表明活化的空气质量从西伯利亚到哈德逊湾运输。为了本地化最可能的运输高度,已经在不同高度中初始化的模型运行显示,在整个对流层中显示出类似的传输模式,但与表面之间的测量和3公里之间的测量值最佳。考虑了对流层高度变化对测量兄弟值的影响,但不能完全解释观察到的高兄弟值。从兄弟初始化区域的后向轨迹显示从表面上向上升降到3公里,没有侵入平流层空气的迹象。这些观察结果与一种情况一致,其中空气质量中的溴在旋风内的表面上被激活,向上抬起并运输超过几千公里到哈德逊湾。

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