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Estimating the influence of transport on aerosol size distributions during new particle formation events

机译:估算新粒子形成事件中运输对气溶胶尺寸分布的影响

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New particle formation (NPF) and subsequent particle growth occur frequently in various atmospheric environments. Significant influence of transport on aerosol size distributions is commonly observed, especially for non-regional NPF events. With certain assumptions and approximations, a population balance method is proposed to examine the influence of transport on the temporal evolution of aerosol size distributions during NPF events. The method is derived from the aerosol general dynamic equation in the continuous form. Meteorological information (e.g., wind speed, wind direction, and water vapor mixing ratio) was used to complement the analysis. The NPF events observed in Southeast Tibet, Fukue Island, and urban Beijing were analyzed using the proposed method. Significant contribution of transport to the observed aerosol size distributions is found during the NPF events in both Southeast Tibet and Fukue Island. The changes in the contribution of transport have a good correlation with the changes in wind speed and direction. This correlation indicates that local mountain and valley breezes govern the observed new particles at the Southeast Tibet site. Most NPF events observed at Fukue Island are closely related to the long-range transport of aerosols and gaseous precursors due to the movement of air masses. Regional NPF events are typically observed in urban Beijing and the contribution of transport to the observed aerosol size distributions is negligible when compared to other processes such as condensational growth and coagulation scavenging. In a relatively clean atmospheric environment, the proposed method can be used to characterize the contribution of transport to particles in the size range from ~10 to ~50nm. During intense NPF events in a relatively polluted atmospheric environment, however, the estimated contribution of transport is sensitive to the uncertainties in condensational growth and coagulation scavenging due to the dominance of their corresponding terms in the population balance equation.
机译:在各种大气环境中经常发生新的颗粒形成(NPF)和随后的颗粒生长。通常会观察到对气溶胶大小分布的运输对气溶胶尺寸分布的显着影响,特别是对于非区域性NPF事件。有一些假设和近似,提出了一种人口平衡方法,以检查运输对NPF事件期间气溶胶尺寸分布的时间演变的影响。该方法以连续形式的气溶胶一般动态方程衍生。气象信息(例如,风速,风向和水蒸气混合比)用于补充分析。使用该方法分析了在东南西藏,福建岛和城市北京市观察的NPF事件。在东南西藏和Fukue岛的NPF事件中发现了运输到观察到的气溶胶尺寸分布的显着贡献。运输贡献的变化与风速和方向的变化具有良好的相关性。这种相关表明,当地山地和山谷布雷兹在东南西藏地区观察到的新颗粒。由于空气质量的运动,在Fukue岛观察到的大多数NPF事件与气溶胶和气体前体的远程运输密切相关。区域NPF事件通常在城市北京观察到,与其他过程相比,近期运输到观察到的气溶胶尺寸分布的贡献可忽略不计,如关节生长和凝固清除。在相对清洁的大气环境中,所提出的方法可用于表征运输到尺寸范围为约10至〜50nm的颗粒的贡献。然而,在相对污染的大气环境中的巨型NPF事件期间,由于在人口平衡方程中的相应术语的主导地位,运输的估计贡献对冷凝生长和凝固凝聚的不确定性敏感。

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