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Seasonal variability of stratospheric methane: implications for constraining tropospheric methane budgets using total column observations

机译:平流层甲烷的季节性变异:使用总柱观察来限制对流层甲烷预算的影响

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Global and regional methane budgets are markedly uncertain. Conventionally, estimates of methane sources are derived by bridging emissions inventories with atmospheric observations employing chemical transport models. The accuracy of this approach requires correctly simulating advection and chemical loss such that modeled methane concentrations scale with surface fluxes. When total column measurements are assimilated into this framework, modeled stratospheric methane introduces additional potential for error. To evaluate the impact of such errors, we compare Total Carbon Column Observing Network (TCCON) and GEOS-Chem total and tropospheric column-averaged dry-air mole fractions of methane. We find that the model's stratospheric contribution to the total column is insensitive to perturbations to the seasonality or distribution of tropospheric emissions or loss. In the Northern Hemisphere, we identify disagreement between the measured and modeled stratospheric contribution, which increases as the tropopause altitude decreases, and a temporal phase lag in the model's tropospheric seasonality driven by transport errors. Within the context of GEOS-Chem, we find that the errors in tropospheric advection partially compensate for the stratospheric methane errors, masking inconsistencies between the modeled and measured tropospheric methane. These seasonally varying errors alias into source attributions resulting from model inversions. In particular, we suggest that the tropospheric phase lag error leads to large misdiagnoses of wetland emissions in the high latitudes of the Northern Hemisphere.
机译:全球和区域甲烷预算显着不确定。传统上,甲烷来源的估计通过桥接具有耐化学传输模型的大气观测的排放清单来源。该方法的准确性需要正确模拟平流和化学损失,使得模型甲烷浓度与表面助熔剂刻度。当总柱测量被同化到该框架中时,建模的平坦散甲烷引入了额外的误差潜力。为了评估这些误差的影响,我们比较总碳柱观察网络(TCCON)和地球化学总和和对流柱柱平均的甲烷的干气摩尔分数。我们发现,该模型对全柱的划线贡献对对流层排放或损失的季节性或分布的扰动不敏感。在北半球,我们确定了测量和建模的平流层贡献之间的分歧,随着对流层的高度降低而增加,模型的对流层季节性的时间滞后是通过运输错误驱动的。在Geos-Chem的背景下,我们发现对流层平流中的误差部分补偿了平流层甲烷误差,掩盖了模拟和测量的对流层甲烷之间的不一致性。这些季节性变化的错误别名才能​​进入模型反转产生的源归因。特别是,我们建议,对流层阶段滞后错误导致北半球高出纬度的湿地排放量大误差。
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