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Mapping the physico-chemical properties of mineral dust in western Africa: mineralogical composition

机译:绘制西非矿物粉尘的物理化学性质:矿物学组合物

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In the last few years, several ground-based and airborne field campaigns have allowed the exploration of the properties and impacts of mineral dust in western Africa, one of the major emission and transport areas worldwide. In this paper, we explore the synthesis of these observations to provide a large-scale quantitative view of the mineralogical composition and its variability according to source region and time after transport. This work reveals that mineral dust in western Africa is a mixture of clays, quartz, iron and titanium oxides, representing at least 92% of the dust mass. Calcite ranged between 0.3 and 8.4% of the dust mass, depending on the origin. Our data do not show a systematic dependence of the dust mineralogical composition on origin; this is to be the case as, in most of the instances, the data represent the composition of the atmospheric burden after 1–2 days after emission, when air masses mix and give rise to a more uniform dust load. This has implications for the representation of the mineral dust composition in regional and global circulation models and in satellite retrievals. Iron oxides account for 58 ± 7% of the mass of elemental Fe and for between 2 and 5% of the dust mass. Most of them are composed of goethite, representing between 52 and 78% of the iron oxide mass. We estimate that titanium oxides account for 1–2% of the dust mass, depending on whether the dust is of Saharan or Sahelian origin. The mineralogical composition is a critical parameter for estimating the radiative and biogeochemical impact of mineral dust. The results regarding dust composition have been used to estimate the optical properties as well as the iron fractional solubility of Saharan and Sahelian dust. Data presented in this paper are provided in numerical form upon email request while they are being turned into a public database, the Dust-Mapped Archived Properties (DUST-MAP), which is an open repository for compositional data from other source regions in Africa and worldwide.
机译:在过去的几年里,几个基于地面和空中的野外运动允许探索西非矿物粉尘的性质和影响,全球主要排放和运输区之一。在本文中,我们探讨了这些观察结果的合成,以根据源区和运输后的时间提供矿物学组合物的大规模定量视图及其可变性。这项工作表明,西非的矿物粉尘是粘土,石英,铁和氧化钛的混合物,代表至少92%的粉尘。方解石在尘埃质量的0.3和8.4%之间,取决于原点。我们的数据没有显示尘埃矿物学组合物原产地的系统依赖性;这是如此,在大多数情况下,数据代表排放后1-2天后大气负担的组成,当空气质量混合并产生更均匀的粉尘载荷。这对区域和全球循环模型和卫星检索的矿物粉尘组合物表示具有影响。氧化铁占元素Fe质量的58±7%,占粉尘质量的2%至5%。它们中的大多数由甲石组成,代表氧化铁质量的52至78%。我们估计钛氧化钛占粉尘质量的1-2%,这取决于灰尘是否是撒哈拉或萨赫洛源。矿物学组合物是用于估计矿物粉尘的辐射和生物地球化学影响的关键参数。关于粉尘组合物的结果已被用于估计光学性质以及撒哈拉和萨赫兰灰尘的铁分数溶解度。本文呈现的数据在电子邮件请求时以数字形式提供,同时它们被转换为公共数据库,灰尘映射的归档属性(灰尘映射),这是来自非洲其他源区的开放存储库全世界。

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