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Aerosol light absorption and the role of extremely low volatility organic compounds

机译:气溶胶光吸收和极低挥发性有机化合物的作用

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A month-long set of summertime measurements in a remote area in the Mediterranean is used to quantify aerosol absorption and the role of black and brown carbon. The suite of instruments included a high-resolution aerosol mass spectrometer (HR-ToF-AMS) and a scanning mobility particle sizer (SMPS), both coupled to a thermodenuder and an Aethalometer, a photoacoustic extinctiometer (PAX405), and a single particle soot photometer (SP2). The average refractory black carbon (rBC) concentration during the campaign was 0.14μgm?3, representing 3% of the fine aerosol mass. The measured light absorption was two or more times higher than that of fresh black carbon (BC). Mie theory indicated that the absorption enhancement due to the coating of BC cores by nonrefractory material could explain only part of this absorption enhancement. The role of brown carbon (BrC) and other non-BC light-absorbing material was then investigated. A good correlation (R2=0.76) between the unexplained absorption and the concentration of extremely low volatility organic compounds (ELVOCs) mass was found.
机译:在地中海的一个偏远地区的夏季测量的长达一个月的一套用于定量气溶胶吸收和黑色和棕色的碳的作用。文书的套件包括一个高分辨率气溶胶质谱仪(HR-TOF-AMS)和一个扫描迁移率粒径仪(SMPS),两者都耦合到thermodenuder和Aethalometer,光声extinctiometer(PAX405),并且单个颗粒烟灰光度计(SP2)。运动过程中的平均耐火炭黑(RBC)的浓度为0.14μgm?3,表示细气溶胶质量的3%。所测得的光吸收比的新鲜黑碳(BC)高两倍或更多倍。米氏理论表明,由于通过nonrefractory材料BC核的涂层的吸收增强可以解释仅此吸收增强的一部分。然后棕色碳(BRC)和其他非BC光吸收材料的作用进行了研究。原因不明的吸收和极低的挥发性有机化合物的浓度之间的良好的相关性(R2 = 0.76)(ELVOCs)质量被发现。

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